Citation: ZHANG Sa, LIU Shou-Xin, HAN Xiao-Yu, DANG Li, QI Xiao-Jun, YANG Xi. Synthesis of P(DEAM-co-NAS) and the Environmental Effects of Its Temperature Sensitivity[J]. Acta Physico-Chimica Sinica, ;2010, 26(08): 2189-2194. doi: 10.3866/PKU.WHXB20100819 shu

Synthesis of P(DEAM-co-NAS) and the Environmental Effects of Its Temperature Sensitivity

1.
Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Materials Science, Shaanxi Normal University, Xi'an 710062, P. R. China

Received Date: 2 March 2010
Available Online: 23 June 2010
Fund Project: 国家自然科学基金(20973106)资助项目 (20973106)

Poly(N,N-diethylacrylamide-co-N-acryloxysuccinimide) (P(DEAM-co-NAS)) was synthesized by free radical solution polymerization and copolymerization ratios of 7.9∶1, 3.5∶1, 2.5∶1, 2∶1, 1.5∶1 were used. The copolymer structures were characterized by Fourier transform infrared (FTIR) spectrometry and nuclear magnetic resonance (¹H NMR). The copolymer compositions and the properties of the medium environment largely influence the temperature sensitivities of the P(DEAM-co-NAS) aqueous solutions. The lower critical solution temperature (LCST) of the P(DEAM-co-NAS) aqueous solution increased with an increase in the NAS content. The addition of salts resulted in a linear decrease in the LCST of the P(DEAM-co-NAS) aqueous solution and this depended on the anion valence of the salts. The addition of organic acids can reduce the LCST of the P(DEAM-co-NAS) aqueous solution. Moreover, the addition of NaOH, ethylenediamine, and putrescine leads to an increase in the LCST of the P(DEAM-co-NAS) aqueous solution. The effects of ethylenediamine and putrescine on the LCST of the P(DEAM-co-NAS) aqueous solution were greater than that of NaOH.
- Temperature sensitivity,
- Poly(N,N-diethylacrylamide-co-N-acryloxysuccinimide),
- Lower critical solution temperature,
- Medium,
- Environmental effect
1. [1]
  
  [1]. Liu, R.; Zhao, X.; Wu, T.; Feng, P. Y. J. Am. Chem. Soc., 2008, 130: 14418
2. [2]
  [2]. Fang, J. Y.; Chen, J. P.; Leu, Y. L.; Hu, J. W. Eur. J. Pharm. Biopharm, 2008, 68: 626
3. [3]
  [3]. You, Y. Z.; Kalebaila, K. K.; Brock, S. L.; Oupicky, D. Chem. Mater., 2008, 20: 3354
4. [4]
  [4]. Gil, E. S.; Hudson, S. M. Prog. Polym. Sci., 2004, 29: 1173
5. [5]
  [5]. Cavalieri, F.; Postma, A.; Lee, L.; Caruso, F. ACS Nano, 2009, 3: 234
6. [6]
  [6]. Maeda, Y.; Sakamoto, J.; Wang, S. Y.; Mizuno, Y. J. Phys. Chem. B, 2009, 113: 12456
7. [7]
  [7]. Liu, W. J.; Huang, Y. M.; Liu, H. L. Acta Chim. Sin., 2007, 65: 91[刘维俊, 黄永民, 刘洪来. 化学学报, 2007, 65: 91]
8. [8]
  [8]. Xia, Y.; Burke, N. A. D.; Stover, H. D. H. Macromolecules, 2006, 39: 2275
9. [9]
  [9]. Barker, I. C.; Cowie, J. M. G.; Huckerby, T. N.; Shaw, D. A.; Soutar, I.; Swanson, L. Macromolecules, 2003, 36: 7765
10. [10]
  [10]. Alarcón, C. D. H.; Pennadam, S.; Alexander, C. Chem. Soc. Rev., 2005, 34: 276
11. [11]
  [11]. Xia, Y.; Yin, X. C.; Burke, N. A. D.; Stover, H. D. H. Macromolecules, 2005, 38: 5937
12. [12]
  [12]. Zhou, K. J.; Lu, Y. J.; Li, J. F.; Shen, L.; Zhang, G. Z.; Xie, Z. W.; Wu, C. Macromolecules, 2008, 41: 8927
13. [13]
  [13]. Flaudy, F. G.; Freitag, R. Langmuir, 2001, 17: 4711
14. [14]
  [14]. Robb, S. A.; Lee, B. H.; Mclemore, R.; Vernon, B. L. Biomacromolecules, 2007, 8: 2294
15. [15]
  [15]. Li, Y. T.; Lokitz, B. S.; McCormick, C. L. Macromolecules, 2006, 39: 81
16. [16]
  [16]. Idziak, I.; Avoce, D.; Lessard, D.; Gravel, D.; Zhu, X. X. Macromolecules, 1999, 32: 1260
17. [17]
  [17]. Stempel, G. H.; Cross, J. R. P.; Mariella, R. P. J. Am .Chem. Soc., 1950, 72: 2299
18. [18]
  [18]. Pollak, A.; Blumenfeld, H.; Wax, M.; Baughn, R. L.; Whitesides, G. M. J. Am. Chem. Soc., 1980, 102: 6324
19. [19]
  [19]. Liu, S. X.; Fang, Y.; Liu, M. Z.; Wang, M. Z.; Wang, Z. R. Acta Chim. Sin., 2006, 64: 1575 [刘守信, 房喻, 柳明珠, 王明珍, 王转绒. 化学学报, 2006, 64: 1575]
20. [20]
  [20]. Zhang, Y. J.; Furyk, S.; Sagle, L. B.; Cho, Y.; Bergbreiter, D. E.; Cremer, P. S. J. Phys. Chem. C, 2007, 111: 8916
21. [21]
  [21]. Dhara, D.; Chatterji, P. R. Polymer, 2000, 41: 6133
22. [22]
  [22]. Freitag, R.; Flaudy, F. G. Langmuir, 2002, 18: 3434
23. [23]
  [23]. Zhang, Y. J.; Furyk, S.; Bergbreiter, D. E.; Cremer, P. S. J. Am. Chem. Soc., 2005, 127: 14505
24. [24]
  [24]. Zhang, J. Y.; Jiang, X. Z.; Zhang, Y. F.; Li, Y. T.; Liu, S. Y. Macromolecules, 2007, 40: 9125
25. [25]
  [25]. Guan, J. J.; Hong, Y.; Ma, Z. W.; Wagner, W. R. Biomacromolecules, 2008, 9: 1283
1. [1]
  Lirui Shen , Kun Liu , Ying Yang , Dongwan Li , Wengui Chang . Synthesis and Application of Decanedioic Acid-N-Hydroxysuccinimide Ester: Exploration of Teaching Reform in Comprehensive Applied Chemistry Experiment. University Chemistry, 2024, 39(8): 212-220. doi: 10.3866/PKU.DXHX202312035
2. [2]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
3. [3]
  Laiying Zhang , Yinghuan Wu , Yazi Yu , Yecheng Xu , Haojie Zhang , Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, 2024, 39(4): 213-220. doi: 10.3866/PKU.DXHX202310126
4. [4]
  Hong Zheng , Xin Peng , Chunwang Yi . The Tale of Caprolactam Cyclic Oligomers: The Ever-changing Life of “Princess Cyclo”. University Chemistry, 2024, 39(9): 40-47. doi: 10.12461/PKU.DXHX202403058
5. [5]
  Yonghui Wang , Weilin Chen , Yangguang Li . Knowledge Construction of “Solubility of Inorganic Substances” in Elemental Chemistry Teaching. University Chemistry, 2024, 39(4): 261-267. doi: 10.3866/PKU.DXHX202312102
6. [6]
  Zijian Zhao , Yanxin Shi , Shicheng Li , Wenhong Ruan , Fang Zhu , Jijun Jiang . A New Exploration of the Preparation of Polyacrylic Acid by Free Radical Polymerization Based on the Concept of Green Chemistry. University Chemistry, 2024, 39(5): 315-324. doi: 10.3866/PKU.DXHX202311094
7. [7]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
8. [8]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
9. [9]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
10. [10]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
11. [11]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
12. [12]
  Xiaofeng Xia , Jielian Zhu . Innovative Comprehensive Experimental Design: Synthesis of 6-Fluoro-N-benzoyl Tetrahydroquinoline. University Chemistry, 2024, 39(10): 344-352. doi: 10.12461/PKU.DXHX202405063
13. [13]
  Keying Qu , Jie Li , Ziqiu Lai , Kai Chen . Unveiling the Mystery of Chirality from Tartaric Acid. University Chemistry, 2024, 39(9): 369-378. doi: 10.12461/PKU.DXHX202310091
14. [14]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
15. [15]
  Yuping Wei , Yiting Wang , Jialiang Jiang , Jinxuan Deng , Hong Zhang , Xiaofei Ma , Junjie Li . Interdisciplinary Teaching Practice——Flexible Wearable Electronic Skin for Low-Temperature Environments. University Chemistry, 2024, 39(10): 261-270. doi: 10.12461/PKU.DXHX202404007
16. [16]
  Meijin Li , Xirong Fu , Xue Zheng , Yuhan Liu , Bao Li . The Marvel of NAD⁺: Nicotinamide Adenine Dinucleotide. University Chemistry, 2024, 39(9): 35-39. doi: 10.12461/PKU.DXHX202401027
17. [17]
  Shaojie Ding , Henan Wang , Xiaojing Dai , Yuru Lv , Xinxin Niu , Ruilian Yin , Fangfang Wu , Wenhui Shi , Wenxian Liu , Xiehong Cao . Mn-modulated Co–N–C oxygen electrocatalysts for robust and temperature-adaptative zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100302-100302. doi: 10.1016/j.cjsc.2024.100302
18. [18]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2023.100416
19. [19]
  Junmei FAN , Wei LIU , Ruitao ZHU , Chenxi QIN , Xiaoling LEI , Haotian WANG , Jiao WANG , Hongfei HAN . High sensitivity detection of baicalein by N, S co-doped carbon dots and their application in biofluids. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2009-2020. doi: 10.11862/CJIC.20240120
20. [20]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005

Get Citation

PDF

XML

Metrics

PDF Downloads(1201)
Abstract views(3199)
HTML views(63)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142