Citation: LI Ya-Juan, ZHAN Hui, LIU Su-Qin, HUANG Ke-Long, ZHOU Yun-Hong. Nanosized Flame Retarded HydroxideMagnesium/Poly(ethylene-oxide) Composite Polymer Electrolyte[J]. Acta Physico-Chimica Sinica, ;2010, 26(09): 2387-2391. doi: 10.3866/PKU.WHXB20100818 shu

Nanosized Flame Retarded HydroxideMagnesium/Poly(ethylene-oxide) Composite Polymer Electrolyte

1.
1. College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China;
2. College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, P. R. China

Received Date: 15 January 2010
Available Online: 23 June 2010
Fund Project: 中国博士后基金(20080440989) (20080440989)高等学校博士学科点专项科研基金(20090162120011)资助项目 (20090162120011)

We prepared nanosized hydroxide magnesium (Mg(OH)₂) as a plasticizer and a flame-retarding additive for a poly(ethylene-oxide) (PEO) based polymer electrolyte. We characterized the prepared compound using transition electron microscopy (TEM), X-ray diffraction (XRD), and thermogravimetry (TG). The prepared hydroxide magnesium particles are hexa nal crystals with sizes of 50-80 nm. The decomposition of the prepared nanosized hydroxide magnesium started at 340 ℃. Electrochemical measurements shows that the ionic conductivity of the Mg(OH)₂/PEO composite polymer electrolytes (CPEs) increases initially and then decreases with an increase in hydroxide magnesium content. It reaches a maximum when the hydroxide magnesium mass fraction is between 5% and 10%. The anodic decomposition potential of the CPEs increases to a certain extent as the hydroxide magnesium content increases. Hydroxide magnesiumhas a positive influence on the electrochemical stability of PEO.
- Lithiumion battery,
- Nanosized hydroxide magnesium,
- Flame-retarding,
- Poly(ethylene-oxide),
- Polymer electrolyte
1. [1]
  
  1. Armand, M. Solid State Ionics, 1994, 69: 309
2. [2]
  2. Glasse, M. D.; Idris, R.; Latham, R. J.; Linford, R. G.; Schlindwein,W. S. Solid State Ionics, 2002, 147: 289
3. [3]
  3. Park, Y. W.; Lee, D. S. J. Non-Cryst. Solids, 2005, 351: 144
4. [4]
  4. Itoh, T.; Hirata, N.; Wen, Z. Y.; Kubo, M.; Yamamoto, O. J. PowerSources, 2001, 97-98: 637
5. [5]
  5. Yu, X. Y.; Xiao, M.; Wang, S. J.; Zhao, Q. Q.; Meng, Y. Z. J. Appl.Polymer Sci., 2010, 115: 2718
6. [6]
  6. Li, X. L.; Guo, J.;Wu, Q.; Cheng, Y.; Long, Y. C.; Jiang, Z. Y.Acta Phys. -Chim. Sin., 2005, 21: 397 [李雪莉,郭娟,吴强,程岩,龙英才, 江志裕. 物理化学学报, 2005, 21: 397]
7. [7]
  7. Sumathipala, H. H.; Hassoun, J.; Panero, S.; Scrosati, B. Ionics,2007, 13: 281
8. [8]
  8. Wang, L. S.; Yang, W. S.; Li, X. W.; Evans, D. G. Electrochem.Solid-State Lett., 2010, 13: A7
9. [9]
  9. Rossi, N. A. A.; West, R. Polym. Int., 2009, 58: 267
10. [10]
  10. Walls, H. J.; Zhou, J.; Yerian, J. A.; Fedkiw, P. S.; Khan, S. A.;Stowe, M. K.; Baker, G. L. J. Power Sources, 2000, 89: 156
11. [11]
  11. Scrosati, B.; Croce, F.; Persi, L. J. Electrochem. Soc., 2000, 147(5): 1718
12. [12]
  12. Kumar, B.; Scanlon, L.; Marsh, R.; Mason, R.; Higgins, R.;Baldwin, R. Electrochim. Acta, 2001, 46: 1515
13. [13]
  13. Croce, F.; Curini, R.; Martinelli, A.; Persi, L.; Ronci, F.; Scrosati,B.; Caminiti, R. J. Phys. Chem. B, 1999, 103: 10632
14. [14]
  14. Sun, H. Y.; Takeda, Y.; Imanishi, N.; Yamamoto, O.; Sohn, H. J.J. Electrochem. Soc., 2000, 147(7): 2462
15. [15]
  15. Appetecchi, G. B.; Dautzenberg, G.; Scrosati, B. J. Electrochem.Soc., 1996, 143(1): 6
16. [16]
  16. Appetecchi, G. B.; Passerini, S. Electrochim. Acta, 2000, 45: 2139
17. [17]
  17. Borkowska, R.; Reda, A.; Zalewska, A.;Wieczorek, W.Electrochim. Acta, 2001, 46: 1737
18. [18]
  18. Aihara, Y.; Kuratomi, J.; Bando, T.; Iguchi, T.; Yoshida, H.; Ono,T.; Kuwana, K. J. Power Sources, 2003, 114: 96
19. [19]
  19. Yoshizawa, M.; Mukai, T.; Ohtake, T.; Kanie, K.; Kato, T.; Ohno,H. Solid State Ionics, 2002, 154-155: 779
20. [20]
  20. Zhang, Z. C.; Sherlock, D.; West, R.; West, R.; Amine, K.; Lyons,L. J. Macromolecules, 2003, 36: 9176
21. [21]
  21. Kang, Y. K.; Lee, J.; Suh, D. H.; Lee, C. J. Power Sources, 2005,146: 391
22. [22]
  22. Liang, Y. H.; Wang, C. C.; Chen, C. Y. Eur. Polym. J., 2008, 44:2376
23. [23]
  23. Hong, L.; Cui, Y. J.;Wang, X. L.; Tang, X. Z. J. Polym. Sci. Pol.Phys., 2003, 41: 120
24. [24]
  24. Yang, X. H.; Sun, X. Y.; Shao, J. J.; Liu, Y. H.; Wang, X. L.J. Polym. Sci. Pol. Phys., 2004, 42: 4195
25. [25]
  25. Bai, Y.; Pan, C. H.; Wu, F.; Wu, C.; Ye, L.; Feng, Z. G. Chem. J.Chin. Univ., 2007, 28: 1796 [白莹,潘春花, 吴锋,吴川,叶霖,冯增国. 高等学校化学学报, 2007, 28: 1796]
26. [26]
  26. Saito, M.; Ikuta, H.; Uchimoto, Y.;Wakihara, M.; Yokoyama, S.;Yabe, T.; Yamamoto, M. J. Phys. Chem. B, 2003, 107: 11608
27. [27]
  27. Croce, F.; Appetecchi, G. B.; Persi, L.; Scrosati, B. Nature, 1998,394: 456.
28. [28]
  28. Jia, X. W. Flame retarding nano-materials. Beijing: ChemicalIndustry Press, 2005 [贾修伟.纳米阻燃材料.北京: 化学工业出版社, 2005]
1. [1]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
2. [2]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
3. [3]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
4. [4]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
5. [5]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
6. [6]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
7. [7]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
8. [8]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-. doi: 10.3866/PKU.WHXB202404023
9. [9]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
10. [10]
  Jiandong Liu , Zhijia Zhang , Mikhail Kamenskii , Filipp Volkov , Svetlana Eliseeva , Jianmin Ma . Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100011-. doi: 10.3866/PKU.WHXB202308048
11. [11]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
12. [12]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
13. [13]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
14. [14]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, 2024, 39(2): 371-378. doi: 10.3866/PKU.DXHX202308057
15. [15]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
16. [16]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
17. [17]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
18. [18]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
19. [19]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
20. [20]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444

Get Citation

PDF

XML

Metrics

PDF Downloads(1177)
Abstract views(3008)
HTML views(17)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142