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Citation: DAI Ke-Hua, MAO Jing, ZHAI Yu-Chun. High Rate Capability of 5 V LiNi0.5Mn1.5O4 Cathode Materials Synthesized via a Gel-Combustion Method[J]. Acta Physico-Chimica Sinica, ;2010, 26(08): 2130-2134. doi: 10.3866/PKU.WHXB20100808 shu

High Rate Capability of 5 V LiNi0.5Mn1.5O4 Cathode Materials Synthesized via a Gel-Combustion Method

  • 1.

    School of Materials and Metallurgy, Northeastern University, Shenyang 110004, P. R. China

  • Received Date: 21 January 2010
    Available Online: 10 June 2010

    Fund Project: 高等学校博士学科点专项科研基金(20090042120013) (20090042120013)沈阳市人才资源开发专项资金(2009010103040)资助项目 (2009010103040)

  • Sub-micron LiNi0.5Mn1.5O4 with excellent high rate performance was synthesized by a polyvinylpyrrolidone-assisted gel-combustion method. Thermogravimetric and differential thermal analyses (TG/DTA) were used to determine the nature of the combustion process of the gel. The structure and morphology of the as-prepared materials were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and cyclic voltammetry (CV). The results showed that the LiNi0.5Mn1.5O4 powders were single-phase spinel and consisted of uniform secondary particles (5 μm), which were formed by small primary particles (500 nm). Galvanostatic charge-discharge tests indicated that the LiNi0.5Mn1.5O4 had an excellent rate capability and cyclic performance. When discharged at a rate of 0.5C, 1C, 4C, 8C,and 10C between 3.5 and 4.9 V, the discharge capacity is 131.9, 127.6, 123.4, 118.4, and 113.7 mAh·g-1, respectively. Upon long cycling under a high discharge rate of 10C, the capacity retentions after 100, 500, and 1000 cycles were 91.4%, 80.9%, and 73.5%, respectively.

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