Citation: YANG Wei-Ben, REN Li. Adsorption Mechanism of Nonylphenol Polyethoxylate onto Hypercrosslinked Resins[J]. Acta Physico-Chimica Sinica, ;2010, 26(08): 2182-2188. doi: 10.3866/PKU.WHXB20100805 shu

Adsorption Mechanism of Nonylphenol Polyethoxylate onto Hypercrosslinked Resins

YANG Wei-Ben ,
REN Li

1.
College of Chemistry and Environment Science, Nanjing Normal University, Nanjing 210097, P. R. China

Received Date: 22 February 2010
Available Online: 7 June 2010
Fund Project: 国家自然科学基金(50978137) (50978137)江苏省自然科学基金(BK2008436)资助项目 (BK2008436)

The aim of this study was to determine the behaviors and mechanism of three hypercrosslinked polymers during the adsorption of nonylphenol ethoxylated decylether (NPEO-10) from aqueous solutions. The polymers were characterized to determine their specific surface areas, pore sizes, and elemental contents. The adsorption isotherms of NPEO-10 on the three polymers fit the Langmuir and double Langmuir models better than the Freundlich model, and the isotherm curves had similar shapes on a lg-lg scale. The amount of adsorbed NPEO-10 depends on the specific surface area, the pore size of the polymer, and the temperature of the solution. Thermodynamic analysis indicated that the adsorption process was characterized by an interaction of the hydrophobic part of the surfactant molecule with the surface of the polymer and by the formation of micelle-like aggregates on the surface of the polymer. A two-dimensional mixture consists of singly dispersed surfactant molecules and monolayered or bi-layered aggregates on the surface of the polymers. Adsorption dynamics confirmed that the adsorption process involved two plateaus which were related to the formation of a monolayer and a bi-layer. Finally, the elution processes were investigated to further establish the appropriate adsorption conditions for the purification of water containing NPEO-10.
- Elution,
- Nonylphenol polyethoxylate,
- Isotherm,
- Resin,
- Temperature
1. [1]
  
  [1]. Hou, S. G.; Sun, H. W.; Gao, Y. Chemosphere, 2006, 63: 31
2. [2]
  [2]. Gioiaa, D. D.; Sciubbaa, L.; Bertina, L. Water Res., 2009, 43: 2977
3. [3]
  [3]. Hu, J. Y.; Chen, X.; Tao, G. Environ. Sci. Technol., 2007, 41: 4097
4. [4]
  [4]. Ike, M.; Asano, M.; Belkada, F. D. Water Sci. Technol., 2002, 46: 127
5. [5]
  [5]. John, D. M.; House, W. A.; White, G. F. Environ. Toxicol. Chem., 2000, 19: 293
6. [6]
  [6]. Misra, K. P.; Dash, U.; Somasundaran, P. Ind. Eng. Chem. Res., 2009, 48: 3403
7. [7]
  [7]. Caruso, F.; Serizawa, T.; Furlong, D. N. Langmuir, 1995, 11: 1546
8. [8]
  [8]. Espantaleón, A. G.; Nieto, J. A.; Fernández, M. Appl. Clay Sci., 2003, 24: 105
9. [9]
  [9]. Nevskaia, D. M.; Sepulveda-Escribano, A.; Guerrero-Ruiz, A. Phys. Chem. Chem. Phys., 2001, 3: 463
10. [10]
  [10]. Streat, M.; Sweetland, L. A. React. Funct. Polym., 1997, 35: 99
11. [11]
  [11]. Penner, N. A.; Nesterenko, P. N. J. Chromatogr. A, 2000, 884: 41
12. [12]
  [12]. Valderrama, C.; Cortina, J. L.; Farran, A. J. Colloid Interface Sci., 2007, 310: 35
13. [13]
  [13]. Tsyurupa, M. P.; Davankov, V. A. React. Funct. Polym., 2002, 53: 193
14. [14]
  [14]. Ahn, J. H.; Jang, J. E.; Oh, C. G. Macromolecules, 2006, 39: 627
15. [15]
  [15]. Yang, W. B.; Li, A. M.; Fan, J. Chemosphere, 2006, 64: 984
16. [16]
  [16]. Valderrama, C.; Gamisans, X.; de las Heras, F. X. React. Funct. Polym., 2007, 67: 1515
17. [17]
  [17]. Streat, M.; Sweetland, L. A. Trans IChemE B, 1998, 76: 115
18. [18]
  [18]. Per, W.; Bengt, J. Langmuir, 1994, 10: 3268
19. [19]
  [19]. Misra, P. K.; Mishra, B. K.; Somasunduran, P. J. Colloid Interface Sci., 2003, 265: 1
20. [20]
  [20]. Shalaby, M. N. Polym. Adv. Technol., 2004, 15: 533
21. [21]
  [21]. Marcel, R. B.; Luuk, K. K. Langmuir, 1992, 8: 2649
22. [22]
  [22]. Li, B. Q.; Eli, R. Langmuir, 1996, 12: 5052
23. [23]
  [23]. nzález-García, C. M.; nzález-Martín, M. L.; Gómez-Serrano, V.; Bruque, J. M.; Labajos-Broncano, L. Langmuir, 2000, 16: 3950
24. [24]
  [24]. Drach, M.; Narkiewicz-Michaek, J.; Rudziński, W. Phys. Chem. Chem. Phys., 2002, 4: 2307
25. [25]
  [25]. Calvoa, E.; Bravoa, R.; Ami a, A. Fluid Phase Equilib., 2009, 282: 14
26. [26]
  [26]. Zhang, R.; Somasundaran, P. Langmuir, 2004, 20: 8552
27. [27]
  [27]. Edwards, D. A.; Adeel, Z.; Luthy, R. G. Environ. Sci. Technol., 1994, 28: 1550
28. [28]
  [28]. Adeel, Z.; Luthy, R. G. Environ. Sci. Technol., 1995, 29: 1032
29. [29]
  [29]. Paria, S.; Yuet, P. K. Ind. Eng. Chem. Res., 2007, 46: 108
30. [30]
  [30]. Liu, Y. J. Chem. Eng. Data, 2009, 54: 1981
31. [31]
  [31]. Urbina-Villalba, G.; Reif, I.; Márquez, M. L. Colloids Surf. A, 1995, 99: 207
32. [32]
  [32]. Levitz, P. E. C. R. Geoscience, 2002, 334: 665
33. [33]
  [33]. Muller, N. Langmuir, 1993, 9: 96
34. [34]
  [34]. Kibbey, T. C. G.; Hayes, K. Environ. Sci. Technol., 1997, 31: 1171
35. [35]
  [35]. Wesemeyer, H.; Muller, B. W.; Muller, R. H. Int. J. Pharm., 1993, 89: 33
36. [36]
  [36]. Ghiaci, M.; Kalbasi, R. J.; Abbaspour, A. Colloids Surf. A, 2007, 297: 105
37. [37]
  [37]. Lindheimer, M.; Keh, E.; Zaini, S.; Partyka, S. J. Colloid Interface Sci., 1990, 138: 83
38. [38]
  [38]. Winnik, M. A.; Bystryak, S. M.; Odrobina, E. Langmuir, 2000, 16: 6118
39. [39]
  [39]. Mishra, S. K.; Kanun , S. B.; Rajeev. J. Colloid Interface Sci., 2003, 267: 42
40. [40]
  [40]. Gallardo-Moreno, A. M.; nzález-García, C. M.; nzález- Martín, M. L.; Bruque, J. M. Colloids Surf. A, 2004, 249: 57
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