Citation:
XU Jia-Xin, JIANG Yan-Xia, LIAO Hong-Gang, CHEN Sheng-Pei, SUN Shi-Gang. Room Temperature Synthesis of Thorn-Like Pd Nanoparticles and Their Enhanced Electrocatalytic Property for Ethanol Oxidation[J]. Acta Physico-Chimica Sinica,
;2010, 26(08): 2139-2143.
doi:
10.3866/PKU.WHXB20100804
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Thorn-like Pd nanoparticles (Pdnthorn000) were synthesized at room temperature by a reduction of PdCl2 with L-ascorbic acid and with choline chloride as a stabilizer. Characterization of Pdthornn000 by transmission electron microscopy and cyclic voltammetry indicated that the synthesized Pdthornn000 has a relatively high density of surface step sites. By comparison with the commercially available Pd black catalyst, Pndthorn000 exhibits better catalytic activity towards ethanol oxidation. The oxidation current density on Pdnthorn000 was 1.2 times (-0.40 - -0.30 V) - 1.5 times (-0.65 - -0.40 V) as that on Pd black, and the onset potential and the peak potential of ethanol oxidation both shifted 50 mV in the negative direction. The oxidation potential of ethanol on Pdthornn000 is lower at the same current density.
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