Citation: YANG Xiao-Deng, SHEN Qiang, XU Gui-Ying. Crystallization of Calcium Carbonate Using Water-Soluble Macromolecules[J]. Acta Physico-Chimica Sinica, ;2010, 26(08): 2087-2095. doi: 10.3866/PKU.WHXB20100639 shu

Crystallization of Calcium Carbonate Using Water-Soluble Macromolecules

1.
Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, P. R. China

Received Date: 26 January 2010
Available Online: 11 May 2010
Fund Project: 国家自然科学基金(20833010)资助项目 (20833010)

The influence of water-soluble macromolecules on the crystallization of calcium carbonate is reviewed combining with our work. The mechanisms are interpreted based on the analysis of calcium carbonate crystallization in the presence of biomacromolecules, synthetic polymers, or mixtures of the polymer and surfactants. This paper provides not only the methods for the crystallization of calcium carbonate consisting of different resultant morphologies, polymorphs, and sizes, but also a theoretical guide for industrial production.
- Water soluble polymer,
- Calcium carbonate,
- Crystallization,
- Polymorph,
- Morphology
1. [1]
  
  [1] Stupp, S. I.; Braun, P. V. Science, 1997, 277: 1242
2. [2]
  [2] Naka, K.; Chujo, Y. Chem. Mater., 2001, 13: 3245
3. [3]
  [3] Cõlfen, H. Curr. Opin. Colloid Interface Sci., 2003, 8: 23
4. [4]
  [4] Politi, Y.; Arad, T.; Klein, E.; Weiner, S.; Addadi, L. Science, 2004, 306: 1161
5. [5]
  [5] Xu, A. W.; Ma, Y.; Cõlfen, H. J. Mater. Chem., 2007, 17: 415
6. [6]
  [6] Porter, S. M. Science, 2007, 316: 1302
7. [7]
  [7] Stanley, S. M. Chem. Rev., 2008, 108: 4483
8. [8]
  [8] Wang, L.; Nancollas, G. H. Chem. Rev., 2008, 108: 4628
9. [9]
  [9] Ouyang, J. M. The modulation and application of matrix in biomimetic mineralization. Beijing: Chemical Industry Press, 2006: 1-45 [欧阳健明. 生物矿化的基质调控及其仿生应用. 北京: 化学工业出版社, 2006: 1-45]
10. [10]
  [10] Mount, A. S.; Wheeler, A. P.; Paradkar, R. P.; Snider, D. Science, 2004, 304: 297
11. [11]
  [11] Sugawara, A.; Kato, T. Chem. Commun., 2000: 487
12. [12]
  [12] Cheng, B.; Lei, M.; Yu, J.; Zhao, X. Mater. Lett., 2004, 58: 1565
13. [13]
  [13] Cui, F. Z. Biomineralization. Beijing. Tsinghua University Press, 2007: 90-156 [崔福斋. 生物矿化. 北京: 清华大学出版社, 2007: 90-156]
14. [14]
  [14] Lochhead, M. J.; Letellier, S. R.; Vogel, V. J. Phys. Chem. B, 1997, 101: 10821
15. [15]
  [15] Wei, H. Controlled mineralization of calcium carbonate by organic additives [D]. Beijing: Institute of Chemistry, Chinese Academy of Sciences, 2005 [魏浩. 有机质对碳酸钙矿化过程机理研究 [D]. 北京: 中国科学院化学研究所, 2005]
16. [16]
  [16] Wolf, S. E.; Loges, N.; Mathiasch, B.; Panth?觟fer, M.; Mey, I.; Janshoff, A.; Tremel, W. Angew. Chem. Int. Edit., 2007, 46: 5618
17. [17]
  [17] Heuer, A.; Fink, D.; Laraia, V.; Arias, J.; Calvert, P.; Kendall, K.; Messing, G.; Blackwell, J.; Rieke, P.; Thompson, D. Science, 1992, 255: 1098
18. [18]
  [18] Mann, S. J. Mater. Chem., 1995, 5: 935
19. [19]
  [19] Mann, S.; Heywood， B． R．; Rajam, S.; Birchall, J. D. Nature, 1988, 334: 692
20. [20]
  [20] Arias, J. L.; Fernàndez, M. S. Chem. Rev., 2008, 108: 4475
21. [21]
  [21] Evans, J. S. Chem. Rev., 2008, 108: 4455
22. [22]
  [22] Dickerson, M. B.; Sandhage, K. H.; Naik, R. R. Chem. Rev., 2008, 108: 4935
23. [23]
  [23] Cusack, M.; Freer, A. Chem. Rev., 2008, 108: 4433
24. [24]
  [24] Sommerdijk, N. A. J. M.; With, G. D. Chem. Rev., 2008, 108: 4499
25. [25]
  [25] Cai, G. B.; Wan, Y.; Yu, S. H. Chin. J. Inorg. Chem., 2008, 24: 673 [蔡国斌, 万勇, 俞书宏. 无机化学学报, 2008, 24: 673]
26. [26]
  [26] Sun, Z. Y.; Huang, J. B. Acta Phys. -Chim. Sin., 2006, 22: 172 [孙振亚, 黄江波. 物理化学学报, 2006, 22: 172]
27. [27]
  [27] Gómez-Morales, J.; Hernández-Hernández, A.; Sazaki, G.; García- Ruiz, J. M. Cryst. Growth Des., 2010, 10: 963
28. [28]
  [28] Tohse, H.; Saruwatari, K.; Kogure, T.; Nagasawa, H.; Takagi, Y. Cryst. Growth Des., 2009, 9: 4897
29. [29]
  [29] Yao, Y.; Dong, W.; Zhu, S.; Yu, X.; Yan, D. Langmuir, 2009, 25: 13238
30. [30]
  [30] Politi, Y.; Batchelor, D. R.; Zaslansky, P.; Chmelka, B. F.; Weaver, J. C.; Sagi, I.; Weiner, S.; Addadi, L. Chem. Mater., 2010, 22: 161
31. [31]
  [31] You, C.; Zhang, Q.; Jiao, Q.; Fu, Z. Cryst. Growth Des., 2009, 9: 4720
32. [32]
  [32] Yamanaka, S.; Ito, N.; Shimosaka, A.; Shirakawa, Y.; Hidaka, J. Cryst. Growth Des., 2009, 9: 3245
33. [33]
  [33] Hou, W.; Feng, Q. J. Cryst. Growth, 2005, 282: 214
34. [34]
  [34] Zhang, Z.; Gao, D.; Zhao, H.; Xie, C.; Guan, G.; Wang, D.; Yu, S. H. J. Phys. Chem. B, 2006, 110: 8613
35. [35]
  [35] Orme, C. A.; Noy, A.; Wierzbicki, A.; McBride, M. T.; Grantham, M.; Teng, H. H.; Dove, P. M.; DeYoreo, J. J. Nature, 2001, 411: 775
36. [36]
  [36] Mao, Z.; Huang, J. J. Solid State Chem., 2007, 180: 453
37. [37]
  [37] Maas, M.; Rehage, H.; Nebel, H.; Epple, M. Colloid. Polym. Sci., 2007, 285: 1301
38. [38]
  [38] Loste, E.; Wilson, R. M.; Seshadri, R.; Meldrum, F. C. J. Cryst. Growth, 2003, 254: 206
39. [39]
  [39] Zhu, L.; Zhao, Q.; Zheng, X.; Xie, Y. J. Solid State Chem., 2006, 179: 1247
40. [40]
  [40] Katsifaras, A.; Spanos, N. J. Gryst. Growth, 1999, 204: 183
41. [41]
  [41] Ajikumar, P. K.; Wong, L. G.; Subramanyam, G.; Lakshminarayanan, R.; Valiyaveettil, S. Cryst. Growth Des., 2005, 5: 1129
42. [42]
  [42] Nishino, Y.; Oaki, Y.; Imai, H. Cryst. Growth Des., 2009, 9: 223
43. [43]
  [43] Vavouraki, A. I.; Putnis, C. V.; Putnis, A.; Koutsoukos, P. G. Chem. Geol., 2008, 253: 243
44. [44]
  [44] Nebel, H.; Epple, M. Z. Anorg. Allg. Chem., 2008, 634: 1439
45. [45]
  [45] Yan, R. X. Water-soluble macromolecules. Beijing: Chemical Industry Press, 1998: 1-41 [严瑞. 水溶性大分子. 北京: 化学工业出版社, 1998: 1-41]
46. [46]
  [46] Yang, X.; Xu, G.; Chen, Y.; Wang, F.; Mao, H.; Sui, W.; Bai, Y.; ng, H. J. Cryst. Growth, 2009, 311: 4558
47. [47]
  [47] Huang, Y.; Shen, Q.; Sui, W.; Guo, M.; Zhao, Y.; Wang, D.; Xu, D. Colloid. Polym. Sci., 2007, 285: 641
48. [48]
  [48] Liang, P.; Shen, Q.; Zhao, Y.; Zhou, Y.; Wei, H.; Lieberwirth, I.; Huang, Y.; Wang, D.; Xu, D. Langmuir, 2004, 20: 10444
49. [49]
  [49] Li, X.; Shen, Q.; Su, Y.; Tian, F.; Zhao, Y.; Wang, D. Cryst. Growth Des., 2009, 9: 3470
50. [50]
  [50] Liang, P.; Zhao, Y.; Shen, Q.; Wang, D.; Xu, D. J. Cryst. Growth, 2004, 261: 571
51. [51]
  [51] Wei, H.; Shen, Q.; Wang, H.; Gao, Y.; Zhao, Y.; Xu, D.; Wang, D. J. Cryst. Growth, 2007, 303: 537
52. [52]
  [52] Shen, Q.; Wei, H.; Zhao, Y.; Wang, D. J.; Zheng, L. Q.; Xu, D. F. Colloid. Surf. A, 2004, 251: 87
53. [53]
  [53] Wei, H.; Shen, Q.; Zhao, Y.; Wang, D.; Xu, D. J. Cryst. Growth, 2004, 260: 545
54. [54]
  [54] Shen, Q.; Wei, H.; Wang, L.; Zhou, Y.; Zhao, Y.; Zhang, Z.; Wang, D.; Xu, G.; Xu, D. J. Phys. Chem. B, 2005, 109: 18342
55. [55]
  [55] Kontrec, J.; Kralj, D.; Brecevic, L.; Falini, G. J. Cryst. Growth, 2008, 310: 4554
56. [56]
  [56] Matahwa, H.; Ramiah, V.; Sanderson, R. D. J. Cryst. Growth, 2008, 310: 4561
57. [57]
  [57] wer, L. B.; Odom, D. J. J. Cryst. Growth, 2000, 210: 719
58. [58]
  [58] Hernández-Hernández, A.; Vidal, M. L.; Gómez-Morales, J.; Rodríguez-Navarro, A. B.; Labas, V.; Gautron, J.; Nys, Y.; Ruíz, J. M. G. J. Cryst. Growth, 2008, 310: 1754
59. [59]
  [59] Díaz-Dosque, M.; Aranda, P.; Darder, M.; Retuert, J.; Yazdani- Pedram, M.; Arias, J. L.; Ruiz-Hitzky, E. J. Cryst. Growth, 2008, 310: 5331
60. [60]
  [60] Sondi, I.; Skapin, S. D.; Salopek-Sondi, B. Cryst. Growth Des., 2008, 8: 435
61. [61]
  [61] Liu, X.; Zhang, L.; Wang, Y.; Guo, C.; Wang, E. Cryst. Growth Des., 2008, 8: 759
62. [62]
  [62] Qi, L.; Li, J.; Ma, J. Adv. Mater., 2002, 14: 300
63. [63]
  [63] Colfen, H.; Qi, L. Chem. Eur. J., 2001, 7: 106
64. [64]
  [64] Gao, Y. X.; Yu, S. H.; Guo, X. H. Langmuir, 2006, 22: 6125
65. [65]
  [65] Gao, Y. X.; Yu, S. H.; Cong, H.; Jiang, J.; Xu, A. W.; Dong, W. F.; Colfen, H. J. Phys. Chem. B, 2006, 110: 6432
66. [66]
  [66] Hernández-Hernández, A.; Rodríguez-Navarro, A. B.; Gómez- Morales, J.; Jiménez-Lopez, C.; Nys, Y.; García-Ruiz, J. M. Cryst. Growth Des., 2008, 8: 1495
67. [67]
  [67] Voinescu, A. E.; Touraud, D.; Lecker, A.; Pfitzner, A.; Kunz, W.; Ninham, B. W. Langmuir, 2007, 23: 12269
68. [68]
  [68] Lee, S. W.; Choi, C. S. Cryst. Growth Des., 2007, 7: 1463
69. [69]
  [69] Wang, X.; Sun, H.; Xia, Y.; Chen, C.; Xu, H.; Shan, H.; Lu, J. R. J. Colloid Interface Sci., 2009, 332: 96
70. [70]
  [70] Roqu, J.; Molera, J.; Vendrell-Saz, M.; Salvad, N. J. Cryst. Growth, 2004, 262: 543
71. [71]
  [71] Shen, F. H.; Feng, Q. L.; Wang, C. M. J. Cryst. Growth, 2002, 242: 239
72. [72]
  [72] Xiang, J.; Cao, H.; Warner, J. H.; Watt, A. A. R. Cryst. Growth Des., 2008, 8: 4583
73. [73]
  [73] Butler, M. F.; Glaser, N.; Weaver, A. C.; Kirkland, M.; Heppenstall-Butler, M. Cryst. Growth Des., 2006, 6: 781
74. [74]
  [74] OlderΦy, M. Φ.; Xie, M. L.; Strand, B. L.; Flaten, E. M.; Sikorski, P.; Andreassen, J. P. Cryst. Growth Des., 2009, 9: 5176
75. [75]
  [75] Sugawara, T.; Suwa, Y.; Ohkawa, K.; Yamamoto, H. Macromol. Rapid Commun., 2003, 24: 847
76. [76]
  [76] Colfen, H.; Mann, S. Angew. Chem. Int. Edit., 2003, 42: 2350
77. [77]
  [77] Wang, T.; Antonietti, M.; Colfen, H. Chem. Eur. J., 2006, 12: 5722
78. [78]
  [78] Yao, C. L. Chin. J. Chem., 2008, 26: 1075
79. [79]
  [79] Shen, X.; Belcher, A. M.; Hansma, P. K.; Stucky, G. D.; Morse, D. E. J. Biol. Chem., 1997, 272: 32472
80. [80]
  [80] Li, J. H.; Yu, P.; Chen, P.; Luo, Y. B. Industrial Water Wastewater, 2006, 37:
81. [81]
  [75] [李江华, 于萍, 陈平, 罗运柏. 工业用水与废水, 2006, 37: 75]
82. [82]
  [81] Liu, Z. F.; Wang, Y. J.; Tian, C. L.; Zhang, Y. H. J. Chem. Ind. Eng., 2006, 57:
83. [83]
  [2361] [刘振法, 王延吉, 田彩莉, 张彦河. 化工学报, 2006, 57: 2361]
84. [84]
  [82] Cheng, Z. H.; Huang, J. L.; Zhang, Y. L.; Yu, X. Y.; Yang, S. L. J. Nanjing Univ. Sci. Technol.: Nature Science, 2007, 31:
85. [85]
  [248] [程志辉, 黄君礼, 张玉玲, 于小英, 杨士林. 南京理工大学学报: 自然科学版, 2007, 31: 248]
86. [86]
  [83] Cao, Y. X.; Yang, J.; Li, J. J. Tongji Univ.: Nature Science, 2004, 32:
87. [87]
  [556] [曹英霞, 杨坚, 李杰. 同济大学学报:自然科学版, 2004, 32: 556]
88. [88]
  [84] Deng, L. Q. Regulation of polymer on calcium oxalate urinary calculi grown in aqueous solutions [M]. Guangzhou: Jinan Unversity,
89. [89]
  [2006] [邓兰青. 聚合物对草酸钙尿路结石的调控作用[M]. 广州: 暨南大学, 2006]
90. [90]
  [85] Carlsen, A.; Lecommandoux, S. Curr. Opin. Colloid Interface Sci., 2009, 14: 329
91. [91]
  [86] Xu, A. W.; Antonietti, M.; Yu, S. H.; Colfen, H. Adv. Mater., 2008, 20: 1333
92. [92]
  [87] Wang, F.; Xu, G. Y.; Zhang, Z. Q.; Xiao, L. Acta Chim. Sin., 2003, 61:
93. [93]
  [1488] [王芳, 徐桂英, 张志庆, 肖莉. 化学学报, 2003, 61: 1488]
94. [94]
  [88] Yu, S. H.; Colfen, H. J. Mater. Chem., 2004, 14: 2124
95. [95]
  [89] Colfen, H.; Yu, S. H. MRS Bulletin, 2005, 30: 727
96. [96]
  [90] Liu, X.; Liu, B.; Wang, Z.; Zhang, B.; Zhang, Z. J. Phys. Chem. C, 2008, 112: 9632
97. [97]
  [91] Huang, J.; Luo, M.; Wang, Y. J. Phys. Chem. B, 2008, 112: 6735
98. [98]
  [92] Castillo, R. V.; Müler, A. J. Prog. Polym. Sci., 2009, 34: 516
99. [99]
  [93] Colfen, H. Macromol. Rapid Commun., 2001, 22: 219
100. [100]
  [94] Guvendiren, M.; Heiney, P. A.; Yang, S. Macromolecules, 2009, 42: 6606
101. [101]
  [95] Zhang, P.; Zhong, X.; Chai, Y.; Liu, Y. Colloid. Polym. Sci., 2008, 286: 1135
102. [102]
  [96] Colfen, H.; Antonietti, M. Langmuir, 1998, 14: 582
103. [103]
  [97] Wada, N.; Kanamura, K.; Umegaki, T. J. Colloid Interface Sci., 2001, 233: 65
104. [104]
  [98] Sedlák, M.; Colfen, H. Macromol. Chem. Phys., 2001, 202: 587
105. [105]
  [99] Yang, H.; Su, Y.; Zhu, H.; Zhu, H.; Xie, B.; Zhao, Y.; Chen, Y.; Wang, D. Polymer, 2007, 48: 4344
106. [106]
  [100] Wang, L.; Meng, Z.; Yu, Y.; Meng, Q.; Chen, D. Polymer, 2008, 49: 1199
107. [107]
  [101] Qi, L.; Colfen, H.; Antonietti, M. Nano Lett., 2000, 1: 61
108. [108]
  [102] Pecher, J.; Guenoun, P.; Chevallard, C. Cryst. Growth Des., 2009, 9: 1306
109. [109]
  [103] He, L.; Xue, R.; Song, R. J. Solid State Chem., 2009, 182: 1082
110. [110]
  [104] Ouhenia, S.; Chateigner, D.; Belkhir, M. A.; Guilmeau, E.; Krauss, C. J. Cryst. Growth, 2008, 310: 2832
111. [111]
  [105] Tang, Y.; Yang, W.; Yin, X.; Liu, Y.; Yin, P.; Wang, J. Desalination, 2008, 228: 55
112. [112]
  [106] Ouyang, X.; Qiu, X.; Lou, H.; Yang, D. Ind. Eng. Chem. Res., 2006, 45: 5716
113. [113]
  [107] Yan, G. W.; Huang, J. H.; Zhang, J. F.; Qian, C. J. Mater. Res. Bull., 2008, 43: 2069
114. [114]
  [108] Jiang, F.; Yang, Y.; Huang, L.; Chen, X.; Shao, Z. J. Appl. Polym. Sci., 2009, 114: 3686
115. [115]
  [109] Kim, R.; Kim, C.; Lee, S.; Kim, J.; Kim, I. W. Cryst. Growth Des., 2009, 9: 4584
116. [116]
  [110] Butler, M. F.; Frith, W. J.; Rawlins, C.; Weaver, A. C.; Heppenstall-Butler, M. Cryst. Growth Des., 2009, 9: 534
117. [117]
  [111] Wu, Q. S.; Sun, D. M.; Liu, H. J.; Ding, Y. P. Cryst. Growth Des., 2004, 4: 717
118. [118]
  [112] Sun, D. M.; Wu, Q. S. Chin. J. Chem., 2004, 22: 1067
119. [119]
  [113] Park, W. K.; Ko, S. J.; Lee, S. W.; Cho, K. H.; Ahn, J. W.; Han, C. J. Cryst. Growth, 2008, 310: 2593
120. [120]
  [114] Nightingale, E. R. J. Phys. Chem., 1959, 63: 1381
121. [121]
  [115] Becker, A.; Ziegler, A.; Epple, M. Dalton Trans., 2005: 1814
122. [122]
  [116] Levi-Kalisman, Y.; Raz, S.; Weiner, S.; Addadi, L.; Sagi, I. Adv. Funct. Mater., 2002, 12: 43
123. [123]
  [117] Meldrum, F. C.; Hyde, S. T. J. Cryst. Growth, 2001, 231: 544
124. [124]
  [118] Zhang, B.; He, P.; Zhang, M. L.; Liang, B.; Xu, S. L. China Surfactant Detergent Cosmetics, 2002, 32: 83 [张彪, 何萍, 张明玲, 梁斌, 徐世玲. 日用化学工业, 2002, 32: 83]
125. [125]
  [119] Chen, Z. P.; Wang, H. X.; Lu, Y. H. China Surfactant Detergent Cosmetics, 2003, 33: 87 [陈志萍, 王红霞, 陆用海. 日用化学工业, 2003, 33: 87]
126. [126]
  [120] Yu, J.; Lei, M.; Cheng, B.; Zhao, X. J. Solid State Chem., 2004, 177: 681
127. [127]
  [121] Tao, C.; Li, J. Langmuir, 2003, 19: 10353
128. [128]
  [122] Tao, C.; Zheng, S.; Mohwald, H.; Li, J. Langmuir, 2003, 19: 9039
129. [129]
  [123] Wang, L.; Chen, X.; Chai, Y.; Hao, J.; Sui, Z.; Zhuang, W.; Sun, Z. Chem. Commun., 2004: 2840
130. [130]
  [124] Wang, L.; Chen, X.; Zhan, J.; Sui, Z.; Zhao, J.; Sun, Z. Chem. Lett., 2004, 33: 720
131. [131]
  [125] Wang, L.; Chen, X.; Zhao, J.; Sui, Z.; Zhuang, W.; Xu, L.; Yang, C. Colloid. Surf. A, 2005, 257-258: 231
132. [132]
  [126] Wang, L.; Chen, X.; Zhan, J.; Chai, Y.; Yang, C.; Xu, L.; Zhuang, W.; Jing, B. J. Phys. Chem. B, 2005, 109: 3189
133. [133]
  [127] Szczes, A.; Chibowski, E.; Holysz, L. Colloid. Surf. A, 2007, 297: 14
134. [134]
  [128] Szczes, A. Colloid. Surf. A, 2008, 320: 98
135. [135]
  [129] Wei, H.; Shen, Q.; Zhao, Y.; Zhou, Y.; Wang, D.; Xu, D. J. Cryst. Growth, 2004, 264: 424
136. [136]
  [130] Dong, S.; Li, X.; Xu, G.; Hoffmann, H. J. Phys. Chem. B, 2007, 111: 5903
137. [137]
  [131] Tjandra, W.; Yao, J.; Ravi, P.; Tam, K. C.; Alamsjah, A. Chem. Mater., 2005, 17: 4865
138. [138]
  [132] Guo, J.; Cao, J. M.; Zheng, M. B.; Deng, S. G.; Jiang, X. H.; Wang, H. Y.; Tao, J. Chin. J. Inorg. Chem., 2007, 23: 725 [郭静, 曹洁明, 郑明波, 邓少高, 蒋锡华, 王海燕, 陶杰. 无机化学学报, 2007, 23: 725]
139. [139]
  [133] Yu, J.; Zhao, X.; Cheng, B.; Zhang, Q. J. Solid State Chem., 2005, 178: 861
140. [140]
  [134] Donners, J. J. J. M.; Heywood, B. R.; Meijer, E. W.; Nolte, R. J. M.; Sommerdijk, N. A. J. M. Chem. Eur. J., 2002, 8: 2561
1. [1]
  Yan Xiao , Shuling Li , Yifan Li , Jianing Fan , Linlin Shi . Discovering the Beauty of Life: Adding Some “Ingredients” to Crystals. University Chemistry, 2024, 39(6): 366-372. doi: 10.3866/PKU.DXHX202312025
2. [2]
  Zhiwen HU , Ping LI , Yulong YANG , Weixia DONG , Qifu BAO . Morphology effects on the piezocatalytic performance of BaTiO₃. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 339-348. doi: 10.11862/CJIC.20240172
3. [3]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
4. [4]
  Juan Yuan , Bin Zhang , Jinping Wu , Mengfan Wang . Design of a Comprehensive Experiment on Preparation and Characterization of Cu₂(Salen)₂ Nanomaterials with Two Distinct Morphologies. University Chemistry, 2024, 39(10): 420-425. doi: 10.3866/PKU.DXHX202402014
5. [5]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
6. [6]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
7. [7]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
8. [8]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
9. [9]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
10. [10]
  Laiying Zhang , Yinghuan Wu , Yazi Yu , Yecheng Xu , Haojie Zhang , Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, 2024, 39(4): 213-220. doi: 10.3866/PKU.DXHX202310126
11. [11]
  Wenjun Yang , Qiaoling Tan , Wenjiao Xie , Xiaoyu Pan , Youyong Yuan . Construction and Characterization of Calcium Alginate Microparticle Drug Delivery System: A Novel Design and Teaching Practice in Polymer Experiments. University Chemistry, 2025, 40(3): 371-380. doi: 10.12461/PKU.DXHX202405150
12. [12]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-. doi: 10.3866/PKU.WHXB202404023
13. [13]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
14. [14]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
15. [15]
  Zhening Lou , Quanxing Mao , Xiaogeng Feng , Lei Zhang , Xu Xu , Yuyang Zhang , Xueyan Liu , Hongling Kang , Dongyang Feng , Yongku Li . Practice of Implementing Blended Teaching in Shared Analytical Chemistry Course. University Chemistry, 2024, 39(2): 263-269. doi: 10.3866/PKU.DXHX202308089
16. [16]
  Zhonghua Xi , Xuanfeng Kong , Jinyue Yang , Bin Liu , Tingyu Zhu , Hui Zhang , Wenwei Zhang . Construction of Public Teaching Instrument Platform and Exploration of Opening Mechanism. University Chemistry, 2024, 39(7): 200-206. doi: 10.12461/PKU.DXHX202405123
17. [17]
  Changyan Sun , Hualei Zhou , Bin Dong . Application of “PBL” Teaching Mode in Inorganic Chemistry Experimental Education in the Perspective of Course Ideology and Politics: Taking Preparation of Manganese Carbonate as an Example. University Chemistry, 2024, 39(11): 378-383. doi: 10.12461/PKU.DXHX202402016
18. [18]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
19. [19]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
20. [20]
  Xiaoyan Wang , Chao Wang , Dongmei Dai , Yanling Geng , Hongtao Gao . Design of Ideological and Political Education for the Experiment on Calcium Content Determination in Calcium Supplements. University Chemistry, 2024, 39(2): 162-167. doi: 10.3866/PKU.DXHX202307074

Get Citation

PDF

XML

Metrics

PDF Downloads(1701)
Abstract views(3320)
HTML views(18)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Crystallization of Calcium Carbonate Using Water-Soluble Macromolecules

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com