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Citation: AN Shen-Jing, GAN Li-Hua, CHEN Liu-Hua, LIU Ming-Xian, ZHU Da-Zhang, XU Zi-Jie, HAO Zhi-Xian, CHEN Long-Wu. Interaction between [1,1'-Binaphthalene]-2,2'-diols and a Solid Supported Bilayer Lipid Membrane[J]. Acta Physico-Chimica Sinica, ;2010, 26(07): 1847-1851. doi: 10.3866/PKU.WHXB20100612 shu

Interaction between [1,1'-Binaphthalene]-2,2'-diols and a Solid Supported Bilayer Lipid Membrane

1.
Department of Chemistry, Tongji University, Shanghai 200092, P. R. China

Received Date: 1 December 2009
Available Online: 22 April 2010

The interaction between [1,1'-binaphthalene]-2,2'-diols (BINOL) and a solid supported bilayer lipid membrane (s-BLM) was studied by cyclic voltammetry and alternating current (AC) impedance measurements. Results indicate that BINOL interacts with s-BLMthrough hydrogen bonding and hydrophobic interaction. The oxidation peak current of the BINOL/s-BLMsystem increases initially and then decreases with an increase in time. This suggests that BINOL gradually destroys the integrity of s-BLM and induces the formation of microchannels within the membrane. The infiltration time of BINOL through the s-BLM decreases as the BINOL concentration increases. With an increase in lecithin and cholesterol content, the membrane resistance of s-BLM increases and the infiltration rate of BINOL through the membrane decreases, which results in a reduction of the infiltration capacity of BINOL towards s-BLM.
- Interaction,
- Solid supported bilayer lipid membrane,
- [1,1'-binaphthalene]-2,2'-diols,
- Infiltration
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