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Citation: WU Jian, WANG Yu, HUANG Feng, YANG Yang, MENG Chang- ng. Thermal Diffusion Synthesis and Characterization of SnO₂ Clusters within ZSM-5 Crystals[J]. Acta Physico-Chimica Sinica, ;2010, 26(06): 1705-1710. doi: 10.3866/PKU.WHXB20100611 shu

Thermal Diffusion Synthesis and Characterization of SnO₂ Clusters within ZSM-5 Crystals

1.
Department of Chemistry, Dalian University of Technology, Dalian 116023, Liaoning Province, P. R. China

Received Date: 22 December 2009
Available Online: 21 April 2010

We used thermal diffusion to load SnO2 into ZSM-5 crystals as it is regarded as a od host material for semiconductor guest encapsulation. The experiments were carried out at 750 and 850 ℃in air. A series of tests were conducted to investigate the basic physical chemistry properties such as chemical composition, crystal images, crystal phase and photoluminescence. An intense porosity analysis based on density functional theory was used to investigate the pore texture of the SnO2-loaded samples. We demonstrate that the SnO2 clusters are located within ZSM-5 instead of on the surface of the crystals. The SnO2 content increases as the thermal diffusion temperature rises. The SnO2 clusters are mainly distributed within the ZSM-5 channels. The sample with a low SnO2 content at 750 ℃ possesses od visible light transmittance and displays od photoluminescence behavior, which makes it a promising material for functionalization and for device-based applications.
- Pore size distribution,
- ZSM-5 crystal,
- Tin dioxide,
- N2 adsorption isotherm,
- Photoluminescence spectrum,
- DFT method
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沈阳化工大学材料科学与工程学院沈阳 110142

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Thermal Diffusion Synthesis and Characterization of SnO2 Clusters within ZSM-5 Crystals

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通讯作者: 陈斌, bchen63@163.com

Thermal Diffusion Synthesis and Characterization of SnO₂ Clusters within ZSM-5 Crystals