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Citation: LIU Jin-Yan, HAN Wai-Hui, ZHANG Yan, YAO Chao-Huai. Studies on the Conductivity ofMixed Reverse Micelles of Anionic and Non-Ionic Surfactants[J]. Acta Physico-Chimica Sinica, ;2010, 26(06): 1552-1556. doi: 10.3866/PKU.WHXB20100536 shu

Studies on the Conductivity ofMixed Reverse Micelles of Anionic and Non-Ionic Surfactants

1.
College of Chemistry and Chemical Engineering, Inner Mon lia University of Science and Technology, Baotou 014010, Inner Mon lia, P. R. China

Received Date: 7 December 2009
Available Online: 9 April 2010

In the SDS/Tween60/hexanol/cyclohexane/water system, a conductivity maximum was observed in the conductivity (κ) and molar ratio of water to surfactants (W0) curves for mixed reverse micelles. The W0,max moved to a bigger W0 value as the xSDS (molar fraction of anionic surfactant) value increased. At xSDS≤0.5, the conductivity values that correspond with W0,max increased as xSDS increased; and at xSDS≥0.5, the conductivity values decreased. In the AOT/Tween60/cyclohexane/water system, the observed phenomenon was similar to the SDS/Tween60/hexanol/cyclohexane/water system. However, conductivity values that correspond with W0,max increased with increasing xAOT and there was no maximum value. The difference is mainly due to cosurfactant effects, which was confirmed by the SDS/TritionX-100/hexanol/cyclohexane/water system.
- Conductivity,
- Mixed system,
- Reverse micelles,
- Solubilization,
- Non-ionic surfactant
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