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Citation: CHANG Yu-Qing, HUANG Ling, SUN Shi-Gang. Electrodeposition and Electrochemical Properties of Ternary Sn-Co-Zn Alloy Electrodes as Anodes for Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2010, 26(03): 561-566. doi: 10.3866/PKU.WHXB20100231 shu

Electrodeposition and Electrochemical Properties of Ternary Sn-Co-Zn Alloy Electrodes as Anodes for Lithium-Ion Batteries

1.
State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received Date: 22 July 2009
Available Online: 4 January 2010

A ternary Sn-Co-Zn alloy film was successfully prepared by electrodepositi on copper foil. Electrochemical deposition of the Sn-Co-Zn alloy was studied by cyclic voltammetry (CV) and chronoamperometry (CA). The structure and electrochemical performance of the electroplated Sn-Co-Zn alloy electrodes were also investigated in detail. The CV and CA results revealed that the initial deposition kinetics of the Sn-Co-Zn alloy corresponds to a model that includes a three-dimensional progressive nucleation and diffusion controlled growth. XRD results showed that the electrodeposited Sn-Co-Zn alloy consists of CoSn3, Co3Sn2, and Zn phase. Electrochemical tests indicated that at the first cycle, the discharge capacity (desertion) and columbic efficiency are measured 751 mAh·g-1 and 88%, respectively, at the 30th cycle, the Sn-Co-Zn alloy electrodes still delivered a discharge capacity of 510 mAh·g-1. The od lithium storage performance of the Sn-Co-Zn electrode is ascribed to multi-phase structure of the electrode.
- Lithium-ion battery,
- Anode,
- Sn-Co-Zn alloy electrode,
- Electrodeposition,
- Electrochemical nucleation and growth
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