Home

Citation: WANG Rui-Xin, JIAO Wei-Zhou, GAO Bao-Jiao. Catalytic Performance of P(4VP-co-St)/SiO₂-Supported Co Tetraphenylporphyrins for the Aerobic Oxidation of Phenylethane[J]. Acta Physico-Chimica Sinica, ;2009, 25(09): 1791-1798. doi: 10.3866/PKU.WHXB20090829 shu

Catalytic Performance of P(4VP-co-St)/SiO₂-Supported Co Tetraphenylporphyrins for the Aerobic Oxidation of Phenylethane

1.
Department of Chemical Engineering, North University of China, Taiyuan 030051, P. R. China

Received Date: 10 February 2009
Available Online: 3 July 2009

The X-substituted cobalt tetraporphyrins (CoTXPP) (X=H, Cl, NO2) were easily bound to the side chains of the grafting particles poly(4-vinyl-pyridine-co-styrene)/SiO2 (P(4VP-co-St)/SiO2) via an axial coordination reaction to prepare supported catalysts CoTXPP-P(4VP-co-St)/SiO2. Structures of the CoTXPP-P(4VP-co-St)/SiO2 catalysts were characterized with FTIR. The axial coordination reaction between the copolymer P(4VP-co-St) and CoTXPP was studied using electronic absorption spectroscopy. Catalytic performances of the supported catalysts for the oxidation of phenylethane in the absence of any reductant or solvent were investigated and compared in detail. Experimental results show that CoTXPP-P(4VP-co-St)/SiO2 can effectively activate dioxygen and obviously catalyze the oxidation of phenylethane to phenylethanone. The catalytic activities of CoTXPP-P(4VP-co-St)/SiO2 increased as the degree of electron deficiency of the peripheral substituent on the porphyrin ring increased. The catalytic activity of CoTNPP-P(4VP-co-St)/SiO2 was found to be the best. At 120 ℃and under the ordinary pressure of oxygen, the catalyst CoTNPP-P(4VP-co-St)/SiO2 gave excellent results with a 25.53%(x) yield of phenylethanone and very little α-phenylethanol. Additionally, we found that: (1) CoTNPP-P(4VP-co-St)/SiO2 as a biomimetic catalyst had an optimumusage amount, and excess addition would decrease the catalyst's efficiency; (2) the immobilization density of CoTXPP on the surface of P(4VP-co-St)/SiO2 still had a maximum value; (3) the catalyst's activity was stable during six catalytic cycles. All these results indicate that the grafted particles P(4VP-co-St)/SiO2 protect the metalloporphyrins from oxidation and also promote the activation of O2 by the metalloporphyrins.
- Catalytic oxidation,
- Poly(4-vinyl-pyridine-co-styrene),
- Grafting particles,
- Axial coordination,
- Supported-metalloporphyrin,
- Phenylethane
1. [1]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
2. [2]
  Chengqian Mao , Yanghan Chen , Haotong Bai , Junru Huang , Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014
3. [3]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
4. [4]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
5. [5]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
6. [6]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
7. [7]
  Ming Li , Zhaoyin Li , Mengzhu Liu , Shaoxiang Luo . Unveiling the Artistry of Mordant Dyeing: The Coordination Chemistry Beneath. University Chemistry, 2024, 39(5): 258-265. doi: 10.3866/PKU.DXHX202311085
8. [8]
  Quanguo Zhai , Peng Zhang , Wenyu Yuan , Ying Wang , Shu'ni Li , Mancheng Hu , Shengli Gao . Reconstructing the “Fundamentals of Coordination Chemistry” in Inorganic Chemistry Course. University Chemistry, 2024, 39(11): 117-130. doi: 10.12461/PKU.DXHX202403065
9. [9]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
10. [10]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
11. [11]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
12. [12]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
13. [13]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
14. [14]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
15. [15]
  Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
16. [16]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
17. [17]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
18. [18]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
19. [19]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
20. [20]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020

Get Citation

PDF

XML

Metrics

PDF Downloads(1309)
Abstract views(2712)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return

Catalytic Performance of P(4VP-co-St)/SiO2-Supported Co Tetraphenylporphyrins for the Aerobic Oxidation of Phenylethane

Metrics

通讯作者: 陈斌, bchen63@163.com

Catalytic Performance of P(4VP-co-St)/SiO₂-Supported Co Tetraphenylporphyrins for the Aerobic Oxidation of Phenylethane