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Citation: ZHANG Li, NIU Shu-Yun, JIN Jing, SUN Li-Ping, SHI Zhong-Feng, LI Lei. Preparation and Light-Induced Surface Electron Behavior of Ni(II) Based on Aromatic Polycarboxyl Acids[J]. Acta Physico-Chimica Sinica, ;2009, 25(06): 1161-1166. doi: 10.3866/PKU.WHXB20090615 shu

Preparation and Light-Induced Surface Electron Behavior of Ni(II) Based on Aromatic Polycarboxyl Acids

1.
College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, Liaoning Province, P. R. China

Received Date: 7 January 2009
Available Online: 6 April 2009

Two nickel coordination complexes [Ni3 (btc)2 (H2O)14]·4H2O(1), [Ni2 (btec) (bipy)2 (H2O)6]·2H2O(2), (H3btc =1,3,5-benzenetricarboxylic acid, H4btec = 1,2,4,5-benzenetetra carboxylic acid, bipy =2, 2'-bipyridyl) were synthesized hydrothermally and characterized by single crystal X-ray diffraction (XRD), infrared (IR) and Ultravialet-Visible-Near Infrared (UV-Vis-NIR) spectra. Result indicate that complex (1) is a trinuclear complex bridged by btc groups and complex (2) is a binuclear complex connected by btec groups. The existence of hydrogen bonds allows complexes (1) and (2) to become coordination supramolecules with three dimensional (3D) and two dimensional (2D) infinite structures, respectively. Surface photovoltage spectrum(SPS) of these complexes exhibits positive surface photovoltage responses from300-800 nm. However, the intensity, position and shape of these response bands are obviously different. This distinction might be responsible for the structures and coordination environments of nickel ions in these complexes. By contrasting SPS with UV-Vis-NIR spectra we find that these response bands in SPS are consistent with absorption peaks in the UV-Vis-NIR spectra.
- Ni(II) coordination supramolecule,
- Crystal structure,
- Hydrogen bond,
- Surface photovoltage
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