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Citation: WANG Jian-She, GUO Xun, SONG Cheng-Ying, WANG Liu-Cheng, ZHAO Jian-Hong, QIU Xin-Ping. Promoting Methanol Electro-Oxidation through Fabricating Pore Structure in Pt/CNTs Catalyst Layer by Dissolving Away Premixed La₂O₃ Particles[J]. Acta Physico-Chimica Sinica, ;2009, 25(04): 767-772. doi: 10.3866/PKU.WHXB200904011 shu

Promoting Methanol Electro-Oxidation through Fabricating Pore Structure in Pt/CNTs Catalyst Layer by Dissolving Away Premixed La₂O₃ Particles

1.
School of Chemical Engineering, Zhengzhou University, Zhengzhou 450000, P. R. China; Key Laboratory of Organic Optoelectronics and Molecular Engineering, Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China

Received Date: 20 November 2008
Available Online: 23 December 2008

To gain insight into the effect of increasing porosity on methanol electro-oxidation, La2O3 particles prepared throughmolten salt method were introduced into a Pt/carbon nanotubes (CNTs) catalyst layer and then dissolved in HClO4, which increased the porosity in the Pt/CNTs catalyst layer. The existence of the as-formed pore structures was confirmed by scanning electronic microscopy (SEM). Cyclic voltammetry (CV) and chronoamperometry methods were used to investigate the effect of increasing porosity, which showed that the methanol electro-oxidizing current was enhanced by 57%. The reason for this result is ascribed to improved methanol access to the Pt surface in the porous catalyst layer. The results indicate that the fabrication of pores in catalyst layer by dissolving away premixed La2O3 particles is an effective method to promote catalyst layer performance.
- Methanol electro-oxidation,
- Catalyst layer,
- Pore-forming agent,
- La2O3 particles,
- Direct methanol fuel cell
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Promoting Methanol Electro-Oxidation through Fabricating Pore Structure in Pt/CNTs Catalyst Layer by Dissolving Away Premixed La2O3 Particles

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通讯作者: 陈斌, bchen63@163.com

Promoting Methanol Electro-Oxidation through Fabricating Pore Structure in Pt/CNTs Catalyst Layer by Dissolving Away Premixed La₂O₃ Particles