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Citation: YU Huang-Zhong, PENG Jun-Biao. Annealing Treatment Effect on Photoelectric Properties of P3HT:PCBMBlend System[J]. Acta Physico-Chimica Sinica, ;2008, 24(05): 905-908. doi: 10.3866/PKU.WHXB20080530 shu

Annealing Treatment Effect on Photoelectric Properties of P3HT:PCBMBlend System

1.
School of Physics, South China University of Technology, Guangzhou 510640, P. R. China; 2Key Laboratory of Specially Functional Materials, Ministry of Education, Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou 510640, P. R. China

Received Date: 14 January 2008
Available Online: 17 March 2008

The effect of annealing treatment on the photoelectric properties of poly(3-hexylthiophene) (P3HT):[6,6]-phenyl-C61-butyric acid methyl ester (PCBM) was analyzed by UV-Vis absorption spectroscopy, photoluminescence (PL) spectroscopy, X-ray diffraction, and solar cell performance. The UV-Vis absorption peaks of P3HT:PCBM thin filmshowed enhancement and a red-shift after thermal annealing. PL and XRD peak intensities increased by annealing treatment. A solar cell based on the blend of P3HT:PCBM was fabricated, and the device performance was significantly improved by thermal annealing. For devices heat-treated at 130 益, open circuit voltage of 0.55 V, short circuit current density of 9.87 mA·cm-2, fill factor of 60.1% and power conversion efficiency (PCE) of 3.26% were achieved under 100 mW·cm-2 air-mass 1.5 solar simulator illumination.
- Annealing treatment; Polymer; Photoelectric properties; Blend system
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