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Citation: ZHAO Qiang, XING Sheng-Kai, ZHANG Qian, SUN De-Zhi. Volumetric Properties of myo-Inositol in Aqueous Alkali Metal Chloride Solutions[J]. Acta Physico-Chimica Sinica, ;2008, 24(05): 890-894. doi: 10.3866/PKU.WHXB20080527 shu

Volumetric Properties of myo-Inositol in Aqueous Alkali Metal Chloride Solutions

1.
College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, Shandong Province, P. R. China

Received Date: 1 November 2007
Available Online: 13 March 2008

Apparent molar volumes (Vφ) of myo-inositol in aqueous solutions of LiCl, NaCl, and KCl were obtained from densities, measured with a vibrating-tube densimeter, at 298.15 and 308.15 K. These data have been used to deduce limiting partial molar volumes Vθφ and limiting partial molar volumes of transfer ⊿trsVθφ from water to different salt solutions at different concentrations. The results indicated that influence of salt (LiCl, NaCl or KCl) on volumetric property of myo-inositol in aqueous solution was evident while temperature could only slightly change Vθφ and ⊿trsVθφ. The result was discussed in the light of interaction between the charged centers of myo-inositol and ions.
- Limiting partial molar volume; myo-Inositol; Alkali metal salt
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