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Citation: ZHANG Lei, WANG Xiao-Chun, NG Qing-Tao, LUO Lan, ZHANG Lu, ZHAO Sui, YU Jia-Yong. Dilational Properties of Tri-substituent Sodium Alkyl Benzene Sulfonates with Different Structures at the Air/Water and Decane/Water Interfaces[J]. Acta Physico-Chimica Sinica, ;2007, 23(12): 1881-1885. doi: 10.3866/PKU.WHXB20071210 shu

Dilational Properties of Tri-substituent Sodium Alkyl Benzene Sulfonates with Different Structures at the Air/Water and Decane/Water Interfaces

1.
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080, P. R. China

Received Date: 10 July 2007
Available Online: 11 October 2007

The dilational rheological properties of a pair of structural isomers: sodium 2-propyl-4,5-dihexyl benzene sulfonate (366) and sodium 2,5-dipropyl-4-nonyl benzene sulfonate(393) at the air/water and decane/water interfaces were investigated by drop shape analysis method. The influences of concentration on dilational modulus were expounded. The experimental results showed that the 5-alkyl played an important role in the surface dilational modulus, while the dimension of surfactant molecule dominated the interfacial dilatinal modulus.
- Sodiumalkyl benzene sulfonate; Surface; Interface; Dilational modulus
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