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Citation: HUANG Xiao-Qing, XUAN Wei-Min, CHEN Lei-Qi, ZHANG Hui, GAO Jing-Xing, . Synthesis, Characterization and Solid-State CD Spectra of the Chiral Bisferrocenyl Ligands[J]. Acta Physico-Chimica Sinica, ;2007, 23(12): 1869-1874. doi: 10.3866/PKU.WHXB20071208 shu

Synthesis, Characterization and Solid-State CD Spectra of the Chiral Bisferrocenyl Ligands

1.
State Key Laboratory for Physical Chemistry of Solid Surface, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Corresponding author: ,
Received Date: 6 August 2007
Available Online: 16 October 2007

A pair of novel chiral tetradentate bisferrocenyl ligands [N,N’-bisferrocenylmethyl-N,N’-bis (2-hydroproxypyl)-(1R,2R)-1,2-diphenylethane-diamine(5R), N,N’-bisferrocenylmethyl-N,N’-bis(2-hydroxypropyl)-(1S,2S)-1,2-diphenylethane diamine (5S)] were synthesized fromferrocenylcarboxaldehyde (1) and chiral 1,2-diphenylethane-diamine (2R or 2S) followed by the reduction of the Schiff bases with NaBH4 and subsequent N-alkylation with 1,2-propyleneoxide. All the chiral products (3R-5S) were charactered by elemental analysis, infrared (IR), 1H nuclear magnetic resonance (1H NMR), ultraviolet-visible (UV-Vis) and solid-state circular dichroism (CD) spectra. The solid-state CDspectra reveal that the chiral characteristics of 5R (or 5S) are quite similar with 4R (or 4S) and it is also notable that there are some differences between 5R (or 5S) and 3R (or 3S).
- Synthesis; Chirality; Bisferrocenyl ligand; Solid-state circular dichroismspectroscopy
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