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Citation: ZHANG Lei, WANG Xiao-Chun, NG Qing-Tao, LUO Lan, ZHANG Lu, ZHAO Sui, YU Jia-Yong. Dynamic Dilational Properties of 2,5-dipropyl-4-undecylbenzene Sulfonate at the Air/Water Interface[J]. Acta Physico-Chimica Sinica, ;2007, 23(10): 1652-1656. doi: 10.3866/PKU.WHXB20071031 shu

Dynamic Dilational Properties of 2,5-dipropyl-4-undecylbenzene Sulfonate at the Air/Water Interface

1.
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080, P. R. China

Received Date: 12 April 2007
Available Online: 2 August 2007

The dynamic dilational viscoelaticity properties of sodium 2,5-dipropyl-4-undecylbenzene sulfonate (3-11-3) at air/water interface were investigated by drop shape analysis. The influences of time, surface pressure, dilational frequency and concentration on surface dilational modulus and phase angle were explored. The experiment results showed that the film was elastic in lower surface pressure range, which was believed to be dominated by the in-surface process. In contrast, the viscous behavior become noticeable in higher surface pressure range, which indicates the diffusion-exchange process between bulk and surface dominates the nature of film.
- Sodiumalkyl benzene sulfonate; Dynamic interfacial dilational property; Dilational modulus; Phase angle
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