Citation: LOU Tai-Ping, WANG Jia-Liang. Ion Exchange Behavior of Na/Li for the Lithium Ion Conductor of LiTi2(PO4)3[J]. Acta Physico-Chimica Sinica, ;2007, 23(10): 1642-1646. doi: 10.3866/PKU.WHXB20071029
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The lithium ion conductor LiTi2(PO4)3 has a very high ion exchange selectivity to Na+ in sodium chloride solution. The ion exchange behavior of Na/Li for LiTi2(PO4)3 in NaCl solution was investigated. The experimental results showed that the Na/Li ion exchange reaction rate increased obviously for LiTi2 (PO4)3 with increasing temperature, and the Na/Li ion exchange kinetics process of LiTi2(PO4)3 in sodium chloride solution could be represented approximately by the equation of JMAK(Johnson-Mehl-Aurami-Kalmo rav). The dissolution behaviors of LiTi2(PO4)3 in water and NaCl solution were investigated, the results showed that higher temperature, acid or alkali environment could enhance the dissolution of LiTi2(PO4)3.
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Keywords:
- LiTi2(PO4)3; Ion exchange; Dissolving
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