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Citation: QIN Hai-Ying, XIE Jian, MI Jian-Li, TU Jian, ZHAO Xin-Bing. Solvothermal Synthesis and Electrochemical Lithiation/Delithiation Performance of FeSb₂ Nanorods[J]. Acta Physico-Chimica Sinica, ;2006, 22(12): 1555-1559. doi: 10.3866/PKU.WHXB20061224 shu

Solvothermal Synthesis and Electrochemical Lithiation/Delithiation Performance of FeSb₂ Nanorods

1.
(State Key Laboratory of Silicon Material, Department of Material Science and Engineering, Zhejiang University, Hangzhou 310027, P. R. China)

Received Date: 25 April 2006
Available Online: 6 December 2006

FeSb2 nanorods, as a potential anode material for lithium-ion batteries, were prepared by solvothermal method in the present work. High-resolution transmission electron microscopy (HRTEM) observations show that the FeSb2 nanorods are 20～40 nm in diameter and 0.2～1.0 μm in length. The charge-discharge measurements and cyclic voltammetry tests reveal that the FeSb2 nanorods exhibit the high initial reversible capacity of 543 mAh•g−1 and an approving cycling stability with 353 mAh•g−1 after 10 cycles. Although the initial coulomb efficiency of the FeSb2 nanorods is only 64%, it is better than that of FeSb2 nano-particles and maintains at 90% after 10 cycles. However, the FeSb2 nanorods could be pulverized and cracked during the cyclic voltammetry test resulting in the failure of the electrode.
- FeSb2 nanorods;Solvothermal synthesis;Anode materials;Lithium-ion batteries
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沈阳化工大学材料科学与工程学院沈阳 110142

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Solvothermal Synthesis and Electrochemical Lithiation/Delithiation Performance of FeSb₂ Nanorods