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Citation: LIU Jin-Yan, ZHAO Jian-Xi, HE Yun-Jing. Micellar Properties of Gemini Surfactants Studied by 1-Naphthylamine Probe[J]. Acta Physico-Chimica Sinica, ;2006, 22(11): 1325-1330. doi: 10.3866/PKU.WHXB20061105 shu

Micellar Properties of Gemini Surfactants Studied by 1-Naphthylamine Probe

1.
Department of Applied Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, P. R. China

Received Date: 17 April 2006
Available Online: 6 November 2006

1-naphthylamine is a probe with intra-molecular charge transfer in nature. Its characteristic band ( ) is sensitive to the polarity of environment. It was found that the semilogarithmic plot of versus surfactant concentration C appeared the two inflection points. The first inflection point corresponded to the critical micelle concentration (cmc), and the second inflection point (Ccm) addressed the critical point reaching dense structure in the micellar core. The results showed that gemini surfactant only form small aggregates at the cmc. Over the range of cmc to Ccm, the aggregation number of the micelle rapidly increases with increasing C.
- Gemini surfactant;1-naphthylamine probe;Micelle growth;The concentration close to the cmc.
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