Citation: JIANG Li-bo, MENG Ai-hua, ZHANG Qi-yun. The Three Pseudo-side-binary Systems in LiCl-(2ZnCl2•KCl)-(ZnCl2•2KCl) System[J]. Acta Physico-Chimica Sinica, ;2006, 22(02): 131-134. doi: 10.3866/PKU.WHXB20060201
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Three pseudo-side-binary systems, LiCl-(2ZnCl2•KCl); LiCl-(ZnCl2•2KCl) and (2ZnCl2•KCl)-(ZnCl2•2KCl) in the pseudo-ternary LiCl-(2ZnCl2•KCl)-(ZnCl2•2KCl), have been investigated by visual-polythermal, DTA and XRD methods. Three new compounds were found in these systems. The ternary compound Li3K2Zn4Cl13 congruently melts at 245 ℃. The incongruent ternary compound Li12K2ZnCl16 and the binary incongruent compound K5Zn4Cl13 peritecticly melt at 432 ℃ and 249 ℃ respectively.
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Keywords:
- Phase diagram;LiCl;KCl;ZnCl2
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