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Citation: ZHOU Xiao-shun, XU Xiaomi, ZHONG Hui-ping, LONG La-sheng, HUANG Rong-bin, XIE Zhao-xiong, ZHENG Lan-sun, MAO Bing-wei. Adsorption of Metal-Organic Complex Molecule on Au(111) Surface[J]. Acta Physico-Chimica Sinica, ;2005, 21(09): 949-951. doi: 10.3866/PKU.WHXB20050901 shu

Adsorption of Metal-Organic Complex Molecule on Au(111) Surface

1.
State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005

Received Date: 25 May 2005
Available Online: 15 September 2005

The adsorption of metal-organic complex molecule ([Cu₂(μ-O)(dptap)4(NO₃)₂], where dptap represents 2-(2-pyridylimino)-2H-1,2,4-thia-diazolo[2,3-a] pyridine) on Au(111) surface is studied by STM. STM results show coexistence of undissociative and dissociative adsorption of the molecule. The former shows regular arrangements of the molecule, while the latter gives a (√3×√3)R30°Cu adlayer structure. The possible origin of the coexistence of undissociative and dissociative adsorption is discussed.
- Molecular self-assembly;Metal-organic complex;Dissociative adsorption;STM
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