Citation: LOU Tai-ping, LI Da-gang, DAI Hou-chen, TANG Shu-huan, XU Tie-wei, GAO Ming. The Ion Exchange Behavior of Na/Li for the Lithium Ion Conductor Li1.3Ti1.7Al0.3(PO4)3;[J]. Acta Physico-Chimica Sinica, ;2005, 21(07): 782-785. doi: 10.3866/PKU.WHXB20050716
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The lithium ion conductor Li1.3Ti1.7Al0.3(PO4)3 is a NASICON structural functional material, which has very high selectivity of ion exchange for Na+. The effects of temperature on Na/Li ion exchange reaction for the Li1.3Ti1.7Al0.3(PO4)3 in sodium chloride and lithium chloride solutions were investigated. The experimental results show that the Na/Li ion exchange reaction rate increases obviously for Li1.3Ti1.7Al0.3(PO4)3 with increasing temperature in the same infiltration time, and the Li1.3Ti1.7Al0.3(PO4)3 is very effective to separate sodium impurity from lithium chloride solution.
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