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Citation: WANG Dong-sheng, HAN Keli, YANG Shi-he. Photo-induced Intra-complex Reactions in Ca⁺-NH₂C(CH₃)₃[J]. Acta Physico-Chimica Sinica, ;2005, 21(06): 583-585. doi: 10.3866/PKU.WHXB20050601 shu

Photo-induced Intra-complex Reactions in Ca⁺-NH₂C(CH₃)₃

1.
Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong；State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023

Received Date: 16 February 2005
Available Online: 15 June 2005

Laser induced reaction of Ca⁺--tertbutylamine complex was studied by reflection time of flight spectrum (RTOF). Different photodissociation spectra, the action spectrum as function of laser wavelength, and ratio curve of different channels were obtained. Two channels were found, one was Ca⁺- cation separation channel, the other one was reactive channel for product Ca⁺-NH₂. Product Ca⁺- was dominant in the whole region studied and the only one in the region 530～595 nm. The action spectrum shows pronounced structureless peaks, which are relevant to the transition of complex. The dynamics of the reaction was discussed at the end.
- Complex;Photodissociation;Atomic orbital;Action spectrum
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沈阳化工大学材料科学与工程学院沈阳 110142

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Photo-induced Intra-complex Reactions in Ca+-NH2C(CH3)3

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通讯作者: 陈斌, bchen63@163.com

Photo-induced Intra-complex Reactions in Ca⁺-NH₂C(CH₃)₃