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Citation: YANG Tao, ZHOU Cong-Shan, ZHU Xin. The Critical Behavior of Benzene-Water-Ethanol Ternary Solutions[J]. Acta Physico-Chimica Sinica, ;2005, 21(04): 439-442. doi: 10.3866/PKU.WHXB20050419 shu

The Critical Behavior of Benzene-Water-Ethanol Ternary Solutions

1.
Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414000

Received Date: 6 August 2004
Available Online: 15 April 2005

The consolute curve of benzene-water-ethanol ternary solutions has been measured by using equal-volume titration, and the coexistence curve near isothermal consolute point at 29.00±0.05 ℃ has also been measured. The obtained order-parameter critical index β = 0.38±0.04, and the order-parameter amplitude K =1.3±0.2. It indicates that near the isothermal consolute point, the critical index of the partly soluble ternary solutions fits Fisher renormalization model well, and it has the character of non-classical critical solution theory.
- Critical phenomena; Order-parameter; Critical index; Isothermal consolute point; 3D-Ising Model; Fisher renormalization model
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