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Citation: MA Zhong-Yi, YANG Cheng, DONG Qing-Nian, WEI Wei, LI Wen-Huai, SUN Yu-Han. A Study of CO₂/H₂ Adsorption on Zirconia Polymorphs[J]. Acta Physico-Chimica Sinica, ;2005, 21(02): 225-228. doi: 10.3866/PKU.WHXB20050224 shu

A Study of CO₂/H₂ Adsorption on Zirconia Polymorphs

1.
StateKeyLaboratoryofCoalConversion,InstituteofCoalChemistry,ChineseAcademyofSciences,Taiyuan　030001;GraduateSchoolofChineseAcademyofSciences,Beijing　100039

Received Date: 4 August 2004
Available Online: 15 February 2005

The adsorption behaviors of CO2 and CO2＋H2 on zirconia polymorphs were investigated by FT-IR technique. The results showed that absorbed CO2 and surface intermediates varied with zirconia polymorphs. Bicarbonate and ion carbonate species were detected on amorphous zirconia. In addition to the two species, bidented carbonate was also formed on monoclinic zirconia. The strongest adsorbed CO2 and polydentate carbonate species were found on tetra nal zirconia. In the case of CO2 hydrogenation, methane was formed on monoclinic zirconia while formate species was observed on tetra nal zirconia.
- Zirconia;FT-IR;CO₂ adsorption;CO₂＋H₂
1. [1]
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4. [4]
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5. [5]
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6. [6]
  Zixuan Zhu , Xianjin Shi , Yongfang Rao , Yu Huang . Recent progress of MgO-based materials in CO₂ adsorption and conversion: Modification methods, reaction condition, and CO₂ hydrogenation. Chinese Chemical Letters, 2024, 35(5): 108954-. doi: 10.1016/j.cclet.2023.108954
7. [7]
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8. [8]
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9. [9]
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10. [10]
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11. [11]
  Yufei Jia , Fei Li , Ke Fan . Surface reconstruction of Cu-based bimetallic catalysts for electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100255-100255. doi: 10.1016/j.cjsc.2024.100255
12. [12]
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13. [13]
  Qin Cheng , Ming Huang , Qingqing Ye , Bangwei Deng , Fan Dong . Indium-based electrocatalysts for CO₂ reduction to C1 products. Chinese Chemical Letters, 2024, 35(6): 109112-. doi: 10.1016/j.cclet.2023.109112
14. [14]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
15. [15]
  Tian-Yu Gao , Xiao-Yan Mo , Shu-Rong Zhang , Yuan-Xu Jiang , Shu-Ping Luo , Jian-Heng Ye , Da-Gang Yu . Visible-light photoredox-catalyzed carboxylation of aryl epoxides with CO₂. Chinese Chemical Letters, 2024, 35(7): 109364-. doi: 10.1016/j.cclet.2023.109364
16. [16]
  Xueyang Zhao , Bangwei Deng , Hongtao Xie , Yizhao Li , Qingqing Ye , Fan Dong . Recent process in developing advanced heterogeneous diatomic-site metal catalysts for electrochemical CO₂ reduction. Chinese Chemical Letters, 2024, 35(7): 109139-. doi: 10.1016/j.cclet.2023.109139
17. [17]
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18. [18]
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19. [19]
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20. [20]
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沈阳化工大学材料科学与工程学院沈阳 110142

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A Study of CO2/H2 Adsorption on Zirconia Polymorphs

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通讯作者: 陈斌, bchen63@163.com

A Study of CO₂/H₂ Adsorption on Zirconia Polymorphs