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Citation: Zhou Xing-Fu, Zhao Jun-Feng, He Hui, Chu Dao-Bao. Electrochemical Dissolution of Tin in Ethylene Glycol Monomethyl Ether and Direct Hydrolysis of the Electrolyte for Preparation of Nano-sized SnO2[J]. Acta Physico-Chimica Sinica, ;2004, 20(12): 1472-1475. doi: 10.3866/PKU.WHXB20041215 shu

Electrochemical Dissolution of Tin in Ethylene Glycol Monomethyl Ether and Direct Hydrolysis of the Electrolyte for Preparation of Nano-sized SnO2

1.
School of Chemistry and Materials Science, Anhui Normal University, Wuhu 241000

Received Date: 13 May 2004
Available Online: 15 December 2004

Metallic tin was directly dissolved in ethylene glycol monomethyl ether and Sn(OCH2CH2OCH3)4 was obtained. The products were characterized by using FT-IR and Raman spectrum. The results show that direct electrochemical preparation of tin complexes has high current efficiency and electrolysis yield, and Sn(OCH2CH2OCH3)4 can be dissolved in ethanol solution and directly used as sol-gel precursor for preparation of nanometer SnO2. The results also show that nano-sized SnO2 prepared by this method has tetra nal cassiterite structure with a narrow size distribution of (10.0±0.4) nm.
- Sn(OCH2CH2OCH3)4;　Tin;　Organic electrolysis preparation;　Sol-gel;　Nano-sized SnO2
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沈阳化工大学材料科学与工程学院沈阳 110142

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