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Citation: Song Ji-Guo, Shen Pei-Kang. Electrochemical Characterization of Copper Paratolylsulfonate[J]. Acta Physico-Chimica Sinica, ;2004, 20(10): 1216-1220. doi: 10.3866/PKU.WHXB20041010 shu

Electrochemical Characterization of Copper Paratolylsulfonate

1.
State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics Science and Engineering, Sun Yat-Sen University, Guangzhou　510275

Received Date: 10 March 2004
Available Online: 15 October 2004

Copper(II) paratolylsulfonate [Cu(p-OTs)]2 has been synthesized and characterized by X-ray crystal structure analysis. The electrochemical parameters of Cu(p-OTs)2 in H2O, CH3OH and DMF have been studied on platinum electrode, respectively. Different reaction mechanisms in different solvents are found. The electrochemical reduction of Cu(II) to Cu proceeds by two one-electron steps in H2O. However, it is a one two-electron process in CH3OH and DMF.
- Copper paratolylsulfonate;Electrochemistry;Cyclic voltammetry;　Mimetic enzyme
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