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Citation: Hua Rui-Mao. Homogeneous Catalytic Activation of Hetero－Carbon Bond and Its Addition to Alkynes[J]. Acta Physico-Chimica Sinica, ;2004, 20(08S): 989-994. doi: 10.3866/PKU.WHXB200408zk15 shu

Homogeneous Catalytic Activation of Hetero－Carbon Bond and Its Addition to Alkynes

Hua Rui-Mao

1.
Key Laboratory of Organic Optoelectronics ＆ Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing　100084

Received Date: 2 January 2004
Available Online: 15 August 2004

This paper reviews the transition metal complexes such as Ni, Pd, Pt, Rh, Cu-catalyzed activation of hetero－carbon bonds and the related catalytic addition reactions with alkynes. These new addition reactions provide one-step, atom-economic methods for the preparation of the functionalized alkenes, which have R3Si, R3Sn, RS, RSe, Cl and Br groups. The addition reactions proceed with high stereoselectivities and regioselectivities.
- Transition metal complex;Hetero－Carbon bond;Activation;Addition reaction;Selectivity
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