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Citation: Nie Chun-Fa, Suo Ji-Shuan. Synthesis,Characterization and Catalytic Applications of Asymmetric Hydrogenation Catalyst Immobilized on Hybrid MCM-41[J]. Acta Physico-Chimica Sinica, ;2004, 20(02): 149-153. doi: 10.3866/PKU.WHXB20040208 shu

Synthesis,Characterization and Catalytic Applications of Asymmetric Hydrogenation Catalyst Immobilized on Hybrid MCM-41

1.
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou　730000;The First Hospital of People’s Liberation Army, Lanzhou　730030

Received Date: 4 August 2003
Available Online: 15 February 2004

Organic-inorganic hybrid mesoporous molecular sieve MCM-41 was synthesized by co-condensation of tetraethoxysilane (TEOS) and 3-chlorpropyl-triethoxysilane, then reacted with (1R,2R)-1,2-diaminocyclohexane and dichloro(p-cymene)-ruthenium dimer successively to afford immobilized asymmetric hydrogen transfer catalyst. The prepared catalyst was characterized by means of FT-IR, PXRD and N2 adsorption-desorption isotherms,and was applied in asymmetric hydrogen transfer reactions of reduction of acetophenone to α-phenyl ethanol. It showed an average conversion of 6.42％ and ee (enantiomeric excess) value of 12.64％ in all 3 performances. The conversion was a little higher than its corresponding homogenous counterpart (conversion of 3.56％ and ee value of 33.04％), while the ee values were somewhat lower.
- Organic-inorganic hybrid;Mesoporous molecular sieve MCM-41;　Asymmetric hydrogen transfer;Immobilized catalyst
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