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Citation: Zhao Li-Li, Wang Rong-Shu. Preparation of MnO₂(Li) and Its Ion Exchange Kinetics[J]. Acta Physico-Chimica Sinica, ;2003, 19(10): 933-937. doi: 10.3866/PKU.WHXB20031010 shu

Preparation of MnO₂(Li) and Its Ion Exchange Kinetics

1.
Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai　200050;

Received Date: 26 April 2003
Available Online: 15 October 2003

The effects of calcination temperatures and extractants on the structure and chemical stability of LiMn2O4 were examined by XRD, βLi (degree of Li＋ extraction) and γMn(degree of Mn2＋ dissolution) analyses, the results show that MnO2(Li) prepared at 750 ℃ for 2 h has larger exchange capacities using (NH4)2S2O8 as extractant. In addition, the mechanism of ion exchange reaction was studied by distribution coefficient measurement and kinetic experiment, and the mathematical model for ion exchange reaction kinetics in a finite solution has been established. The results indicate that this ion exchange process is controlled by particle diffusion; ion exchange reaction mainly occurs in the outer layer of MnO2(Li). The experimental results are in od agreement with the calculated values.
- Extractant of Li^＋;LiMn₂O₄;MnO₂(Li) exchanger;Kinetics
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沈阳化工大学材料科学与工程学院沈阳 110142

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Preparation of MnO2(Li) and Its Ion Exchange Kinetics

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com

Preparation of MnO₂(Li) and Its Ion Exchange Kinetics