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Citation: Ning Bin, Fan Lou-Zhen, Zheng Li-Ping, Cao Yong, Guo Zhi-Xin. Electrochemical Properties of Methanofullerenes[J]. Acta Physico-Chimica Sinica, ;2003, 19(10): 917-921. doi: 10.3866/PKU.WHXB20031007 shu

Electrochemical Properties of Methanofullerenes

1.
Department of Chemistry, Beijing Normal University, Beijing　100875; Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou　510640;Institute of Chemistry, Chinese Academy of Sciences, Beijing　100080

Received Date: 8 April 2003
Available Online: 15 October 2003

11 methanofullerenes have been investigated using cyclic voltammetry(CV) systematically and comparatively. The influence of the nature of groups introduced and chain length of substituents on the electron-accepting ability of methanofullerenes was observed. It was found that introducing electron-donating groups, such as alkyls, weaken the electron- accepting ability of C60 and make its first reduction wave shifted to more negative position. Introducing electron-withdrawing groups, such as carboxylic ester groups, compensate part of negative shift of the reduction wave due to the effect of the saturation of a fullerene double bond. It was also found that increasing the chain length of substituents would not obviously change the electron-accepting ability of C60. Furthermore, the split of reduction peaks of some methanofullerenes induced by electrochemical isomerization was explained.
- Fullerene;Methanofullerene;Cyclic voltammetry(CV);Electrochemical properties;Isomerization
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