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Citation: An Zeng-Jian, Zhou Peng, Jian Xi-Gao, Cai Tian-Xi. Sulfonated Poly (phthalazinone ether sulfone ketone) Catalyst with High Thermal Stability[J]. Acta Physico-Chimica Sinica, ;2003, 19(07): 654-656. doi: 10.3866/PKU.WHXB20030718 shu

Sulfonated Poly (phthalazinone ether sulfone ketone) Catalyst with High Thermal Stability

1.
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian　116012

Received Date: 5 December 2002
Available Online: 15 July 2003

A new solid acid resin catalyst with high thermal stability——sulfonated poly (phthalazinone ether sulfone ketone) (S-PPESK) resin was prepared through sulfonation method and applied to isobutene oli merization. S-PPESK showed high catalytic activity and excellent dimerization selectivity under low reaction temperature conditions. The thermal stability of S-PPESK was measured by pretreatment method, the pretreatment temperature was 180 ℃ which was about 40 ℃ higher than that for with commercial sulphuric acid resin catalyst. S-PPESK exhibits od catalytic activity, excellent dimerization selectivity and high thermal stability in isobutene oli merization. It is a promising resin catalyst.
- Sulfonated poly (phthalazinone ether sulfone ketone, S-PPESK);　　Isobutene oli merization;Thermal stability
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