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Citation: Bi Hui-Min, Che Hui-Juan, Zheng Shi-Jun, Meng Ling-Peng, Wang Dian-Xun. Gas-Solid Reaction Mechanism of X₂ (X=Cl,Br) and A CN under the Condition of Super Vacuum[J]. Acta Physico-Chimica Sinica, ;2003, 19(03): 272-274. doi: 10.3866/PKU.WHXB20030319 shu

Gas-Solid Reaction Mechanism of X₂ (X=Cl,Br) and A CN under the Condition of Super Vacuum

1.
College of Chemistry, Hebei Normal University, Shijiazhuang　050091; Institute of Chemistry, Chinese Academy of Sciences, Beijing　10080

Received Date: 2 July 2002
Available Online: 15 March 2003

The gas-solid heterogeneous reaction between X2 (X=Cl, Br) and A CN has been investigated under the condition of super vacuum, HeI photoelectron spectroscopy (PES) indicates that XNCO was produced, and we deduce that an inter mediate complex in this process was formed, i.e. the generation of new-bond and the broken of old-bond were ing simultaneously.
- Gas-solid heterogeneous reaction;HeI photoelectron spectroscopy(PES); A CN
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Gas-Solid Reaction Mechanism of X2 (X=Cl,Br) and A CN under the Condition of Super Vacuum

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通讯作者: 陈斌, bchen63@163.com

Gas-Solid Reaction Mechanism of X₂ (X=Cl,Br) and A CN under the Condition of Super Vacuum