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Citation: Zhang Xian-Yi, Kong Xiang-Lei, Luo Xiao-Lin, Li Yi-Min, Li Hai-Yang. Study on Visible Chemiluminescence from Reaction of O(³P) Atom with Carbon Disulfide[J]. Acta Physico-Chimica Sinica, ;2003, 19(03): 260-264. doi: 10.3866/PKU.WHXB20030316 shu

Study on Visible Chemiluminescence from Reaction of O(³P) Atom with Carbon Disulfide

1.
Laboratory of Environmental Spectroscopy, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei　230031; College of Physics and Electronic Information, Anhui Normal University, Wuhu　241000

Received Date: 3 June 2002
Available Online: 15 March 2003

Visible Chemiluminescence in the region of 380～500 nm was measured from the reaction of O( 3P ) atoms with carbon disulfide under various pressures using crossed molecular beam apparatus. The emission spectra were assigned to 3B1→ 1A1 transition of gaseous sulfur dioxide molecules. 3B1 state of sulfur dioxide is mainly composed of vibrational ground state and excited vibrational state of bending vibrational mode, vibrational band progressions in the lower state of bending modes and stretching modes were observed. The spectra under various pressures and the reaction mechanism were discussed. It was proposed that 3B1 state of sulfur dioxide was produced from multistage processes.
- Crossed molecular beam;Chemiluminescence;Gas-phase reaction
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Study on Visible Chemiluminescence from Reaction of O(3P) Atom with Carbon Disulfide

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通讯作者: 陈斌, bchen63@163.com

Study on Visible Chemiluminescence from Reaction of O(³P) Atom with Carbon Disulfide