Citation: Ruan Sheng-Ping, Dong Wei, Wu Feng-Qing, Wang Yong-Wei, Yu Tao, Peng Zeng-Hui, Xuan Li. Dielectric Properties of Nanocrystalline BaTiO3[J]. Acta Physico-Chimica Sinica, ;2003, 19(01): 17-20. doi: 10.3866/PKU.WHXB20030105
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Nanocrystalline BaTiO3 is prepared using a stearic acid gel method. The synthesis process, crystalline structure and grain sizes of nanocrystal are investigated by differential thermal analysis, thermogravimetric analysis, infrared spectra and X-ray powder diffraction. The experimental results of dielectric properties of nanocrystal indicate that the dielectric constant ε of nanocrystal is much larger than that of bulk materials. With reducing of grain size, the ε of nanocrystalline material increases first, then it falls to smaller value. With the increment of relative humidity, the ε grows up. The relationship between ε and humidity becomes linear with high enough humidity.
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