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Citation: An Zeng-Jian, Zhou Peng, Jian Xi-Gao, Cai Tian-Xi. Catalytic Activity of Sulfonated Poly (phthalazinone ether sulfone ketone) Resin[J]. Acta Physico-Chimica Sinica, ;2003, 19(01): 1-3. doi: 10.3866/PKU.WHXB20030101 shu

Catalytic Activity of Sulfonated Poly (phthalazinone ether sulfone ketone) Resin

1.
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian　116012

Received Date: 10 September 2002
Available Online: 15 January 2003

A novel sulfonated poly (phthalazinone ether sulfone ketone) resin catalyst (S-PPESK) was prepared by means of sulfonation method and characterized with titration. The catalytic activity of this new resin catalyst in the isobutene oli merization was measured in detail; it exhibited od catalytic activity and excellent isobutene dimerization selectivity. The results indicated that when the sulfonation degree (S.D.) of the catalyst increased, i.e. the acid volume of the catalyst increased, the conversion for isobutene and the selectivity for trimer increased also, while the selectivity for dimer decreased, and the selectivity for tetramer was almost unchanged.
- S-PPESK;Sulfonation degree (S.D.);Catalytic activity;Isobutene oli merization
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