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Citation: Chen Ming-Dan, Hu Sheng-Zhi. Study on the Bond Valance Parameters Related to Lanthanoid[J]. Acta Physico-Chimica Sinica, ;2002, 18(12): 1104-1109. doi: 10.3866/PKU.WHXB20021210 shu

Study on the Bond Valance Parameters Related to Lanthanoid

1.
State Key Laboratory for Physical Chemistry of Solid Surfaces, Institute of Physical Chemistry, Department of Chemistry, Xiamen University, Xiamen　361005

Received Date: 27 March 2002
Available Online: 15 December 2002

Based on the crystal structure data of the lanthanide complexes, lanthanide contraction of the single valance bond length R0 for Ln－O bond is confirmed. The R0 values with B=0.037 nm were re-determined systematically as described by the linear equation R0 (nm)=0.2879－0.00132N, where N is the atomic number of lanthanide. Using the parameters suggested by Brown-O′Keeffe and the present authors, the bond valance sums for Ln(III) in some organometallic compounds were calculated and discussed in detail. Prospects for the further studies in the line of bond valence parameters were briefly presented.
- Bond valance parameter;Lanthanide contraction;Bond valance sum
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