Citation: Zhu Xiao-Yang. Organic Monolayers on Silicon:Microprinting, Micromachines, and Microarrrays[J]. Acta Physico-Chimica Sinica, ;2002, 18(09): 855-864. doi: 10.3866/PKU.WHXB20020919
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This account summarizes recent research in my laboratory on the integration of organic functionalities to silicon surfaces. We have discovered and developed novel, two-step strategies for the assembly of organic monolayers on silicon, silica, and related materials. These methods are simple and reproducible and lead to close packed monolayers with excellent physical/chemical properties. Exciting applications of these monolayers include (a) resists in soft-lithography, particularly micro-contact printing; (b) monolayer lubricant in silicon based micromachines, also called micro electromechanic systems (MEMS); and (c) molecular basis for the immobilization of DNA and protein molecules in microarrays.
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