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Citation: Yan Yun, Han Feng, Huang Jian-Bin, Li Zi-Chen, Ma Ji-Ming. The Study of Bolaamphiphile/SDS Mixed Systems by Applying the Regular Solution Theory[J]. Acta Physico-Chimica Sinica, ;2002, 18(09): 830-834. doi: 10.3866/PKU.WHXB20020913 shu

The Study of Bolaamphiphile/SDS Mixed Systems by Applying the Regular Solution Theory

1.
College of Chemistry and Molecular Engineering, Peking University，Beijing　100871

Received Date: 25 January 2002
Available Online: 15 September 2002

The interaction of molecules on the surface and in the micelle of the mixed system of cationic bolaamphiphile/sodium dodecyl sulfate(SDS) was studied by using regular solution theory. The interaction parameter indicates that strong interaction exists both in the surface adsorption layer and in the micelle. The strength of the interaction is similar to that of conventional alkyl quaternary ammonium salt/alkyl sodium sulfate mixed system. This means the synergism in the bolaamphiphile/SDS mixed system is mainly caused by the electrostatic interaction between the hydrophilic head group, but not apparently affected by the hydrophobic part of the bola molecules.
- Regular solution theory;Bolaamphiphile;Interaction;Micelle;Surface adsorption layer
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