Citation: Kong Yong, Mu Shao-Lin. Electrochemical Polymerization of Thionine and Properties of Polythionine[J]. Acta Physico-Chimica Sinica, ;2001, 17(04): 295-299. doi: 10.3866/PKU.WHXB20010403
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The electrochemical polymerization of thionine in the aqueous acetic solution has been carried out using cyclic voltammetry. Polythionine is a blue material. Its color can be quickly changed by applied potential. Polythionine has a od electrochemical reversibility, stability and a fast charge transfer ability in the solution of 0.50 mol•dm-3 HCl to the solution of acetate of pH 6.0. Visible and FTIR spectra of polythionine have been presented in this paper. Based on FTIR spectra, a suggestion for mechanism of polymerization of thionine is presented.
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