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Citation: Liu Shu-Qing, Xu Ji-Qing, Sun Hao-Ran, Li Dong-Mei, Zeng Qing-Xin, Song Yu-Jiang. Spectra and Electrocatalytic Reduction of Dioxygen of Mesotetrakis (4Nbenzylpyridyl)porphyrinmetaloxo Cluster Supramolecular Complex[J]. Acta Physico-Chimica Sinica, ;2001, 17(02): 128-133. doi: 10.3866/PKU.WHXB20010208 shu

Spectra and Electrocatalytic Reduction of Dioxygen of Mesotetrakis (4Nbenzylpyridyl)porphyrinmetaloxo Cluster Supramolecular Complex

1.
Department of Chemistry,Jilin University,Changchun　130023

Received Date: 27 April 2000
Available Online: 15 February 2001

Spectral behavior of mesotetrakis(4Nbenzylpyridyl)porphyrinmetaloxo cluster (SiW12O4－40) supramolecular systems in aqueous solution was studied by UVvisible spectrometry.The spectral evolution and Job's plots reveal that the stable aggregates contain equal numbers of the cationic porphyrins and the anionic SiW12O4－40.The electrocatalytic behavior of reducing O2 for the 1∶1 supramolecular complex [CoTMPyP][SiW12O40],was also investigated,the supramolecular complex might be hopeful for being used as a new material of modified electrodes for electrocatalytic reduction of O2.
- Cationic porphyrin;Metal-oxo cluster anions;Supramolecular complex;　Electrocatalytic reduction of O₂
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