Citation:
Wang Hui, Liu Jian-Xun, Wang Bao-Shan, Kong Fan-Ao. IR Emission Spectra and the Product Channels of the Reaction of C2H3 with O2[J]. Acta Physico-Chimica Sinica,
;2000, 16(08): 674-676.
doi:
10.3866/PKU.WHXB20000801
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The reaction of vinyl radicals with oxygen was investigated by Time-Resolved Fourier Transform infrared emission spectroscopy. The radicals were produced by the pulsed laser photolysis of C_2H_3Br at 248 nm. Vibrationally excited products of H_2CO(v1), HCO(v3), CO_2(v3, v), CH_3(v3), C_2H_2(v3), HO_2(v1), C_2H_2O_2(v3+v11), CO(v) formed in the C2H3+O_2 reaction have been observed. Four elementary reaction channels have been verified.
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Keywords:
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Vinyl
, - O2,
- IR emission spectra,
- Elementary reaction channels
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