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Citation: Zhou Jia-Hong, Xue Kuan-Hong, Sun Dong-Mei, Xu Shi-Min, Kong Jing-Lin. AC Impednce Study of the Aqueous Zn/V₂O₅ Secondary Battery[J]. Acta Physico-Chimica Sinica, ;2000, 16(05): 454-458. doi: 10.3866/PKU.WHXB20000516 shu

AC Impednce Study of the Aqueous Zn/V₂O₅ Secondary Battery

1.
Department of Chemistry,Nanjing Normal University,Nanjing 210097

Received Date: 9 August 1999
Available Online: 15 May 2000

The dependence of charge transfer resistances of electrodes in the aqueous Zn/V 2O 5 secondary battery on the Zn 2+ amount intercalated was studied by means of AC impedance experiments. The results showed that the electrode reaction on cathode was controlled by the diffusion of Zn 2+ at the beginning of the discharge process. With the increase of Zn 2+ amount intercalated into the cathode, the reaction became a kinetic controlled process, i.e.a process controlled by intercalation of Zn 2+ in V 2O 5.
- Secondary battery,
- Zinc battery,
- V₂O₅,
- Impedance
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沈阳化工大学材料科学与工程学院沈阳 110142

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AC Impednce Study of the Aqueous Zn/V2O5 Secondary Battery

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通讯作者: 陈斌, bchen63@163.com

AC Impednce Study of the Aqueous Zn/V₂O₅ Secondary Battery