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Citation: Guo Wen-Yue, Fang Li, Zhang Bing, Zhang Shu-Dong, Cai Ji-Ye. Multiphoton lonization Spectrum of the 3d Rydberg States of 2-butanone[J]. Acta Physico-Chimica Sinica, ;1999, 15(11): 976-979. doi: 10.3866/PKU.WHXB19991104 shu

Multiphoton lonization Spectrum of the 3d Rydberg States of 2-butanone

1.
Anhui Institute of Optics and Mechanics,Academia Sinica,Hefei 230031

Received Date: 29 June 1999
Available Online: 15 November 1999

The resonance-enhanced multiphoton ionization (REMPI) spectrum of 2 butanone in 467～488nm was obtained using multiphoton ionization—time-of-flight mass spectrometric technique and dye laser. By analyzing the spectrum, we have ascertained that the strongest peak in the REMPI spectrum,62305cm-1,could be attributed to one component of the 3d Rydberg transition, the peaks in 63291～63898cm-1 are mixed Rydberg valence vibronic transitions, and 63291cm-1 is the 0-0 transition of the state.
- 2-butanone;Rydberg state,
- Mixed Rydberg-valence state,
- Multiphoton ionization spectrum
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