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Citation: Miao Fang-Ming, Fan Zhi, Zhou Wei-Hong, Qi Li-Ning, Li Ai-Xiu, Liu Xiao-Lan. Synthesis and Crystal Structure and Quantum Chemistry of Tris(2-benzimidazylmethyl)amine with Manganese(II)[J]. Acta Physico-Chimica Sinica, ;1999, 15(09): 775-782. doi: 10.3866/PKU.WHXB19990902 shu

Synthesis and Crystal Structure and Quantum Chemistry of Tris(2-benzimidazylmethyl)amine with Manganese(II)

1.
Institute of Chemical Crystallography,Tianjin Normal University,Tianjin 300074

Received Date: 16 November 1998
Available Online: 15 September 1999

A new complex of tris(2-benzimidazylmethyl)amine (NTB) with manganese(II) was synthesized. Single crystal X ray diffraction studies show that this new compound belongs to monoclinic, space group P2 1/c with a = 1.423 8(7) nm, b = 2.480 2(3) nm, c =1.697 7(7) nm, V = 5.989 3nm 3 and Z = 4 The crystal structure was solved by heavy atom and Fourier synthesis methods, the structure was refined to R = 0 07 The coordinated number of Mn 2+ is five with a distorted tri nal bipyramid geometry. The quantum chemistry calculation shows that Mn 2+ cation locates itself in the middle of the negative charge hole formed by five nitrogen atoms.
- Manganese(II),
- Synthesis,
- Crystal structure,
- Tris(2-benzimidazylmethyl)amine
  ,
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