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Citation: Feng Hai-Xia, Zhu Zhi-Ang, Wang Chuan-Zhong, Ruan Wen-Juan, Li Ying, Chen Rong-Ti. Kinetics on the Axial Coordination Reaction of Co(II)-2,9,16,23-tetracaboxyphthalocyanine with 2-mercaptoethanol[J]. Acta Physico-Chimica Sinica, ;1999, 15(02): 167-172. doi: 10.3866/PKU.WHXB19990214 shu

Kinetics on the Axial Coordination Reaction of Co(II)-2,9,16,23-tetracaboxyphthalocyanine with 2-mercaptoethanol

1.
Department of Chemistry,Nankai University,Tianjin 300071

Received Date: 24 April 1998
Available Online: 15 February 1999

The kinetic studies on the axial coordination reaction of Co(Ⅱ)-2,9,16,23-tetracaboxyphthalocyamine with 2-mercaptoethanol in aqueous solution were studied by stopped flow method. A general mechanism was proposed and the kinetic parameters were obtained by non-liner and liner least-squares program. The effects of temperature and pH on the reaction were investigated in this paper.
- Co(II)-Phthalocyanine,
- Thiol,
- Kinetics of axial coordinational reaction,
- Stopped flow method
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