Citation:
Yu Chun-Ying, Li Wen-Zhao, Wang Jun, Chen Yan-Xin, Zhang Ying-Zhen. Effect of Supported Pt on Reduction and Sulfidation of Mo Based Catalysts[J]. Acta Physico-Chimica Sinica,
;1998, 14(05): 439-443.
doi:
10.3866/PKU.WHXB19980511
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Effect of supported Pt on reduction and sulfidation for Pt/MoO3 and Pt/MOS2 catalysts were studied by pulse reduction-sulfidation, flow reduction-sulfidation, temperature programmed electrical conductivity, temperature programmed reduction technique and X ray diffraction analysis. It was found that, for Pt/MoO3 the addition of Pt greatly promoted the reduction and sulfidation of MoO3, it was also shown that, for Pt/MoS2 Pt obviously facilitated the reduction of MoS2 to form S-vacancy, leading to an increment of the concentration of coordinative unsaturated molybdenum.
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Keywords:
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MoO3
, - Pt/MoO3,
- TPR,
- XRD,
- Electrical conductivity
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