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Citation: Yu Jian-Feng, Qin Du-Jie, Wu Tong-Hao, Wang Guo-Jia, Sun Jia-Zhong. The Repair Effect of Transition-Metal lons on the Lacunary Heteropoly Complexes with Keggin Structure[J]. Acta Physico-Chimica Sinica, ;1998, 14(05): 435-438. doi: 10.3866/PKU.WHXB19980510 shu

The Repair Effect of Transition-Metal lons on the Lacunary Heteropoly Complexes with Keggin Structure

1.
Department of Chemistry,Institute Chemistry,Changchun 130023

Received Date: 29 August 1997
Available Online: 15 May 1998

The 4th period transition-metal lacunary monosubstituted molybdophosphoric and tungstophosphoric complexes with Keggin structrue were synthesized. The synthesis conditions were discussed. The repair effect of the changing of the transition- metal ions electronic configuration on the substituted ligands was characterizated by the vibration of P-O.
- Transition-metal of the 4th period,
- Heteropoly complexes with Keggin structure,
- Lacunary monosubstitution,
- Vibration of P-O
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